27825-35-0Relevant academic research and scientific papers
A Phosphino-Carboxylic Acid-Based Ru Dimeric Complex
Rank, Christian K.,Wall, Tatjana,Dietrich, Fabian,Vidovic, Marko,Klein, Matthias P.,Sun, Yu,Niedner-Schatteburg, Gereon,Gerhards, Markus,Patureau, Frederic W.
, p. 1394 - 1398 (2018)
A new supramolecular Ru dimer is described, notably by X-ray crystallography, ESI-MS and solution IR spectroscopy. The properties and C–H bond activation catalytic activity of this new H-bonded binuclear complex are discussed.
Accelerated Ru–Cu Trinuclear Cooperative C?H Bond Functionalization of Carbazoles: A Kinetic and Computational Investigation
Jones, Alexander W.,Rank, Christian K.,Becker, Yanik,Malchau, Christian,Funes-Ardoiz, Ignacio,Maseras, Feliu,Patureau, Frederic W.
supporting information, p. 15178 - 15184 (2018/09/25)
The mechanism of a trinuclear cooperative dehydrogenative C?N bond-forming reaction is investigated in this work, which avoids the use of chelate-assisting directing groups. Two new highly efficient Ru/Cu co-catalyzed systems were identified, allowing orders of magnitude greater TOFs than the previous state of the art. In-depth kinetic studies were performed in combination with advanced DFT calculations, which reveal a decisive rate-determining trinuclear Ru–Cu cooperative reductive elimination step (CRE).
ORGANIC COMPOUND AND ORGANIC OPTOELECTRIC DEVICE AND DISPLAY DEVICE
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Paragraph 0145-0147, (2017/10/20)
The present invention relates to an organic compound represented by chemical formula 1, and an organic photoelectronic device and a display apparatus comprising the organic compound. In the chemical formula 1, X, L, R^1 to R^8 are the same as defined in the specification.
Toward polynuclear Ru-Cu catalytic dehydrogenative C-N bond formation, on the reactivity of carbazoles
Louillat, Marie-Laure,Patureau, Frederic W.
supporting information, p. 164 - 167 (2013/03/28)
The cooperative action of Ru and Cu catalysts enables direct polynuclear C-H and N-H activation for the dehydrogenative N-carbazolation of carbazoles, selectively at the C1 position. Initial mechanistic experiments are presented and discussed.
