27829-63-6

Upstream product

• 186641-79-2 (R)-4-((tert-Butyldiphenylsilyl)oxy)-3-methylbutanal 
• 930120-99-3 (+)-(3S,5S,7R,9R)-10-(tert-butyl-diphenyl-silanyloxy)-3,5,7,9-tetramethyl-decan-1-ol 
• 930120-95-9 (+)-(E)-(5R,7R)-8-(tert-butyl-diphenyl-silanyloxy)-5,7-dimethyl-oct-2-enethioic acid S-ethyl ester 
• 930120-92-6 (+)-(E)-(R)-6-(tert-butyl-diphenyl-silanyloxy)-5-methyl-hex-2-enethioic acid S-ethyl ester 
• 917590-87-5 (R)-4-(tert-butyl-diphenyl-silanyloxy)-3-methyl-thiobutyric acid S-ethyl ester 
• 930121-01-0 (+)-(2R,4R,6R,8R)tert-butyl-diphenyl-(2,4,6,8-tetramethyl-octacosyloxy)-silane 
• 930121-00-9 (+)-(3S,5S,7R,9R)-toluene-4-sulfonic acid 10-(tert-butyl-diphenyl-silanyloxy)-3,5,7,9-tetramethyl-decyl ester 
• 930120-97-1 (+)-(E)-(5S,7R,9R)-10-(tert-butyl-diphenyl-silanyloxy)-5,7,9-trimethyl-dec-2-enethioic acid S-ethyl ester 

Relevant academic research and scientific papers

Catalytic asymmetric synthesis of mycocerosic acid

The first catalytic asymmetric total synthesis of mycocerosic acid was achieved via the application of iterative enantioselective 1,4-addition reactions and allows for the efficient construction of 1,3-polymethyl arrays with full stereocontrol; further exemplified by the synthesis of tetramethyl-decanoic acid, a component of the preen-gland wax of the graylag goose, Anser anser. The Royal Society of Chemistry.