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(Z)-2-Methyl-2-butenoic acid [(1S,2R,7aR)-hexahydro-2β-hydroxy-1H-pyrrolizin-1β-yl]methyl ester is a complex organic compound that features a pyrrolizidine alkaloid structure. It is derived from the plant Senecio amphibolus and S. macrophylla MB, and is characterized by its unique stereochemistry and the presence of a methyl ester group. (Z)-2-Methyl-2-butenoic acid [(1S,2R,7aR)-hexahydro-2β-hydroxy-1H-pyrrolizin-1β-yl]methyl ester forms a low melting solid and has not yet been obtained in a crystalline form. It exhibits dextrorotatory optical activity with a specific rotation of [α]20D + 34.52° (c 1.68, EtOH). Upon hydrolysis with dilute acids, it yields macronecine and angelic acid, and has been characterized as the crystalline bitartrate with a melting point of 162-4°C.

27841-97-0

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  • (Z)-2-Methyl-2-butenoic acid [(1S,2R,7aR)-hexahydro-2| -hydroxy-1H-pyrrolizin-1| -yl]methyl ester

    Cas No: 27841-97-0

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  • (Z)-2-Methyl-2-butenoic acid [(1S,2R,7aR)-hexahydro-2β-hydroxy-1H-pyrrolizin-1β-yl]methyl ester

    Cas No: 27841-97-0

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27841-97-0 Usage

Uses

Used in Pharmaceutical Industry:
(Z)-2-Methyl-2-butenoic acid [(1S,2R,7aR)-hexahydro-2β-hydroxy-1H-pyrrolizin-1β-yl]methyl ester could be used as a pharmaceutical compound for its potential therapeutic properties. Pyrrolizidine alkaloids are known for their diverse biological activities, and (Z)-2-Methyl-2-butenoic acid [(1S,2R,7aR)-hexahydro-2β-hydroxy-1H-pyrrolizin-1β-yl]methyl ester may exhibit medicinal properties that could be harnessed for the development of new drugs.
Used in Chemical Research:
In the field of chemical research, (Z)-2-Methyl-2-butenoic acid [(1S,2R,7aR)-hexahydro-2β-hydroxy-1H-pyrrolizin-1β-yl]methyl ester may serve as a subject for studying the synthesis, structure, and properties of complex organic molecules. Its unique stereochemistry and the presence of a methyl ester group could provide valuable insights into the behavior of similar compounds and contribute to the advancement of organic chemistry.

References

Danilova et al.,J. Gen. Chem. USSR, 23,1417 (1953) Danilova, Kuzovkov, ibid, 23,1597 (1953) Danilova, Utkin, Massagetov, ibid, 25, 797 (1955) Danilova, Utkin, ibid, 30, 345 (1960) Culvenor, Geissman,J. Org. Chem., 26, 3045 (1961)

Check Digit Verification of cas no

The CAS Registry Mumber 27841-97-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,7,8,4 and 1 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 27841-97:
(7*2)+(6*7)+(5*8)+(4*4)+(3*1)+(2*9)+(1*7)=140
140 % 10 = 0
So 27841-97-0 is a valid CAS Registry Number.
InChI:InChI=1/C13H21NO3/c1-3-9(2)13(16)17-8-10-11-5-4-6-14(11)7-12(10)15/h3,10-12,15H,4-8H2,1-2H3/b9-3-/t10-,11-,12+/m1/s1

27841-97-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name [(1S,2R,8R)-2-hydroxy-2,3,5,6,7,8-hexahydro-1H-pyrrolizin-1-yl]methyl (Z)-2-methylbut-2-enoate

1.2 Other means of identification

Product number -
Other names Macrophylline

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:27841-97-0 SDS

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