27842-13-3

Basic information

• Product Name: L-Alanine, N-(N-acetyl-D-phenylalanyl)-, methyl ester
• CAS NO: 27842-13-3
• Molecular Formula: C15H20N2O4
• Molecular Weight: 292.335
• Mol File: 27842-13-3.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: L-Alanine, N-(N-acetyl-D-phenylalanyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: L-Alanine, N-(N-acetyl-D-phenylalanyl)-, methyl ester(27842-13-3)
• EPA Substance Registry System: L-Alanine, N-(N-acetyl-D-phenylalanyl)-, methyl ester(27842-13-3)

Safety Data

• Hazardous Substances Data: 27842-13-3(Hazardous Substances Data)

Upstream product

• 94943-62-1 Ac-Δ-Ph-(S)-Ala-OCH3 
• 76741-30-5 (S)-2-((3R,4S)-3-Acetylamino-2-oxo-4-phenyl-azetidin-1-yl)-propionic acid methyl ester 
• 76741-28-1 (3R,4S,1'S)-1-(1'-Methoxycarbonyl)ethyl-3-azido-4-phenylazetidin-2-one 
• 53933-42-9 2-(benzylidene-amino)-propionic acid methyl ester 
• 55065-02-6 N-acetamido cinnamic acid 
• 42291-21-4 AcΔPheAlaOH 
• 65941-25-5 Ac-ΔPhe-(S)-Ala-OH 
• 2018-61-3 (S)-2-acetylamino-3-phenylpropanoic acid 
• 2491-20-5 L-alanine methyl ester hydrochloride 
• 543-27-1 isobutyl chloroformate 
• 74986-31-5 AcΔPhe(RS)AlaOMe 

Relevant articles and documents

Chiral sulfonated phosphines. VIII. Hydrogenation of dehydropeptides in a two-phase system

Dehydropeptides have been reduced in a two-phase system using 2> associated with chiral water-soluble ligands derived from cyclobutanediop and BDPP.Diastereoselectivities of up to 87percent were obtained with tetrasulfonated BDPP.

Effects of solvent and temperature on the 1,4-asymmetric induction in the diastereoselective hydrogenation of dehydrodipeptides

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ASYMMETRIC HYDROGENATION OF DEHYDRODIPEPTIDES WITH RHODIUM(I)-CHIRAL DIPHOSPHINITES. SELECTIVE (S,S)- AND (R,R)-PRODUCT FORMATION BY DOUBLE ASYMMETRIC INDUCTION.

In the hydrogenation of dehydrodipeptides, the effect of chiral center of the substrate ((S) or (R)) on the asymmetric induction was examined using the catalysts of Rh(I)-chiral diphosphinite containing pyrrolidine moiety (POP). The catalysts with POP's h