2793-54-6Relevant articles and documents
Kinetics, Isotope Effects, and Mechanism of the Reaction of 1,1,1-Trifluoro-2,2-bis-(4-nitrophenyl)ethane with Piperidine and Pyrrolidine Bases in Dipolar Aprotic Solvents
Jarczewski, Arnold,Schroeder, Grzegorz,Dworniczak, Miroslaw
, p. 55 - 60 (1986)
The kinetics of the reaction of 1,1,1-trifluoro-2,2-bis-(4-nitrophenyl)ethane with piperidine and pyrrolidine bases in a series of solvents are reported.The reaction is complex, le
Solvolysis of 1-Aryl-2,2,2-trifluoroethyl Sulfonates. Kinetic and Stereochemical Effects in the Generation of Highly Electron-Deficient Carbocations
Allen, Annette D.,Ambidge, I. Christopher,Che, Claudius,Micheal, Hany,Muir, Ronald J.,Tidwell, Thomas T.
, p. 2343 - 2350 (2007/10/02)
Solvolysis rates of sulfonates XC6H4CH(O3SR)CF3 (R = p-Tol or CF3) correlate with ?+(X) with values of ρ+ between -6.7 and -11.9 depending upon solvent.For the tosylates the rates depend on the solvent parameter YOTs with