27935-87-1

Basic information

• Product Name: IODOMETHYLCYCLOPENTANE
• Synonyms: IODOMETHYLCYCLOPENTANE;CYCLOPENTYL METHYL IODIDE;Iodomethylcyclopentane, stabilized, 98%;Cyclopentanemethyl iodide;(Iodomethyl)cyclopentane, 98+%, stab. with copper;Iodomethylcyclopentane, 98%, stabilized;IodoMethylcyclopentane, stabilized, 98% 5GR;(Iodomethyl)cyclopentane, stabilized with copper
• CAS NO: 27935-87-1
• Molecular Formula: C₆H₁₁I
• Molecular Weight: 210.06
• Mol File: 27935-87-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 78°C/17mm
• Flash Point: 92 °C
• Appearance: Clear colorless to yellow to light orange or light brown/Solution
• Density: 1.6
• Vapor Pressure: 0.746mmHg at 25°C
• Refractive Index: 1.54-1.544
• Sensitive: Light Sensitive
• CAS DataBase Reference: IODOMETHYLCYCLOPENTANE(CAS DataBase Reference)
• NIST Chemistry Reference: IODOMETHYLCYCLOPENTANE(27935-87-1)
• EPA Substance Registry System: IODOMETHYLCYCLOPENTANE(27935-87-1)

Safety Data

• Hazard Codes: Xi,T
• Statements: 36-65-53-41-37/38-25
• Safety Statements: 37/39-26-62-45-39
• RIDADR: UN 2810 6.1 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 27935-87-1(Hazardous Substances Data)

Usage

Chemical Properties

Clear liquid

Synthesis Reference(s)

Tetrahedron Letters, 27, p. 5821, 1986 DOI: 10.1016/S0040-4039(00)85336-8

InChI:InChI=1/C6H11I/c7-5-6-3-1-2-4-6/h6H,1-5H2

Upstream product

• 18922-04-8 6-iodohex-1-ene 

Downstream Products

• 1123-00-8 2-cyclopentylacetic acid 
• 1003013-43-1 3-cyclopentyl-N-(2(R)-hydroxy-1(R)-methyl-2(R)-phenyl-ethyl)-N-methyl-2(R)-(3-trifluoromethyl-phenyl)-propionamide 
• 436141-39-8 3-cyclopentyl-N-[2(R)-hydroxy-1(R)-methyl-2(R)-phenyl-ethyl]-N-methyl-2(R)-(4-methylsulfanyl-phenyl)-propionamide 
• 300355-27-5 3-cyclopentyl-2-(4-nitro-phenyl)-propionic acid ethyl ester 
• 866774-35-8 3-cyclopentyl-2-[4-(4-methyl-piperazine-1-sulfonyl)phenyl]propionic acid ethyl ester 
• 372509-76-7 3-cyclopentyl-2-(4-morpholin-4-yl-phenyl)-propionic acid methyl ester 
• 300355-19-5 3-cyclopentyl-2-(4-methanesulfonyl-phenyl)propionic acid methyl ester 
• 588940-74-3 (2R)-2-[3-chloro-4-(methylsulfanyl)phenyl]-3-cyclopentyl-N-[(1R,2R)-1-hydroxy-1-phenylpropan-2-yl]-N-methylpropanamide 
• 588939-42-8 3-cyclopentyl-2-(4-methoxymethylsulfanyl-phenyl)-propionic acid 
• 1043908-67-3 4-([1,2,4]triazolo[1,5-a]pyridin-6-yl)-1-(cyclopentylmethyl)-5-methyl-3-m-tolyl-1H-imidazol-2(3H)-one 

Relevant articles and documents

ATOM TRANSFER CYCLIZATION OF SIMPLE HEXENYL IODIDES. A CAUTION ON THE USE OF ALKENYL IODIDES AS PROBES FOR THE DETECTION OF SINGLE ELECTRON TRANSFER PROCESSES

The trialkyltin initiated isomerization of 1-iodo-5-hexene to (iodomethyl)cyclopentane is reported.Rapid and reversible iodine atom transfer between alkyl radicals is the key chain transfer step.The results suggest an important caution in the use of hexenyl iodides as SET probes: a good mechanism exists whereby the yield of rearranged products may be much greater than the amount of radicals produced by the reaction under study!