279683-29-3Relevant academic research and scientific papers
Metal-catalyzed oxidation and epoxidation of α-hydroxy vinyl and dienyl sulfoxides
De La Pradilla, Roberta Fernandez,Castellanos, Alejandro,Fernandez, Jorge,Lorenzo, Milagros,Manzano, Pilar,Mendez, Paloma,Priego, Julian,Viso, Aima
, p. 1569 - 1575 (2007/10/03)
Treatment of acyclic α-hydroxyalkyl α,β-unsaturated sulfoxides with t-BuOOH/VO(acac)2 results in rapid oxidation to the unsaturated sulfones followed by an unusual regio- and stereoselective epoxidation at the unsaturated sulfones; this methodo
Highly diastereoselective dihydroxylation of cis-substituted sulfonyl vinyl oxiranes
Fernández De La Pradilla, Roberto,Méndez, Paloma,Viso, Alma
, p. 2871 - 2874 (2007/10/03)
An expedient route to rare carbohydrate-like fragments that relies on the highly stereoselective osmium-catalyzed dihydroxylation of 2-sulfonyl-2- hydroxyalkyl-3-vinyloxiranes is outlined. (C) 2000 Elsevier Science Ltd.
