28022-22-2

Upstream product

• 16484-04-1 2-Azido-1-iodo-3-phenylpropan 
• 10147-11-2 propargyl benzene 
• 300-57-2 allylbenzene 

Downstream Products

• 49656-73-7 4-benzyl-5-methoxy-5-trifluoromethyl-2,5-dihydro-oxazole 
• 135608-75-2 benzyl carbamate 
• 18709-44-9 C₉H₉N 
• 49656-77-1 4-benzyl-2H-oxazol-5-one 

Relevant academic research and scientific papers

Electrocatalytic Synthesis of gem -Bisarylthio Enamines and α-Phenylthio Ketones via a Radical Process under Mild Conditions

The novel method for the synthesis of gem -bisarylthio enamines and α-phenylthio ketones was developed via the coupling of α-substituted vinyl azides with thiols in the presence of tetrabutylammonium iodide (TBAI) as a redox catalyst and electrolyte at ro

AgN3-Catalyzed Hydroazidation of Terminal Alkynes and Mechanistic Studies

The hydroazidation of alkynes is the most straightforward way to access vinyl azides-versatile building blocks in organic synthesis. We previously realized such a fundamental reaction of terminal alkynes using Ag2CO3 as a catalyst. H

Transformation of Alkynes into α- Or β-Difluorinated Alkyl Azides by an Efficient One-Pot Two-Step Procedure

Reported herein an unprecedented 1,2-azide migratory hydroazidation and subsequent gem-difluorination of alkynes accessing β-difluorinated alkyl azides. Importantly, functional group controlled 1,2-azide or 1,2-aryl migration was observed in the case of a

Radical Enamination of Vinyl Azides: Direct Synthesis of N-Unprotected Enamines

An electron-withdrawing-group-generable radical-induced enamination of vinyl azides is reported, which results in a variety of β-functionalized N-unprotected enamines in a stereoselective manner. A plausible mechanism involving an unusual 1,3-H transfer of in situ generated iminyl radical intermediate was proposed on the basis of experimental results and DFT calculations.