28022-32-4Relevant academic research and scientific papers
SUBSTITUENT EFFECTS ON THE REGIO- AND STEREOSELECTIVITY OF GAS-PHASE ACID-INDUCED RING OPENING IN 1-ARYLCYCLOHEXENE OXIDES
Cecchi, P.,Pizzabiocca, A.,Renzi,G.,Chini, M.,Crotti, P.,et al.
, p. 4227 - 4234 (2007/10/02)
Comparative analysisof the ratio of the isomeric monomethyl ethers of 1-arylcyclohexane-1,2-diols formed in the gas-phase and solvolytic acid-induced methanolysis of several 1-arylcyclohexene oxides indicates the intrinsic electronic factors detrminimg the regio- and stereochemical course of the nucleophilic attack, related to the partial degree of carbocationic character at the reaction centre in the substitution transition state.
