28035-71-4

Upstream product

• 5176-28-3 N-(tert-butoxycarbonyl)-1,4-dihydro-1,4-iminonaphthalene 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 18271-17-5 N-tosyl-1-naphthylamine 
• 1254703-44-0 (1R,2R)-N-[2-(4-propylphenylamino)-1,2-dihydronaphthalen-1-yl]-4-methylbenzenesulfonamide 
• 1254703-42-8 (1R,2R)-N-[2-(p-toluidino)-1,2-dihydronaphthalen-1-yl]-4-methyl-benzenesulfonamide 
• 1254703-38-2 (1R,2R)-N-[2-(ethyl(phenyl)amino)-1,2-dihydronaphthalen-1-yl]-4-methylbenzenesulfonamide 
• 1254703-39-3 (1R,2R)-N-[2-(methyl-m-tolylamino)-1,2-dihydronaphthalen-1-yl]-4-methylbenzenesulfonamide 
• 1254703-43-9 (1R,2R)-N-[2-(2,4-dimethoxyphenylamino)-1,2-dihydronaphthalen-1-yl]-4-methylbenzenesulfonamide 
• 1254703-37-1 (1R,2R)-4-methyl-N-[2-(methyl(phenyl)amino)-1,2-dihydronaphthalen-1-yl]-benzenesulfonamide 
• 1254703-45-1 (1R,2R)-N-[2-(4-bromophenylamino)-1,2-dihydronaphthalen-1-yl]-4-methylbenzenesulfonamide 

Relevant academic research and scientific papers

CATALYSTS FOR EFFICIENT Z-SELECTIVE METATHESIS

The present application provides, among other things, compounds and methods for metathesis reactions. In some embodiments, provided compounds promote highly efficient and highly Z-selective metathesis. In some embodiments, provided compounds and methods are particularly useful for producing allyl alcohols. In some embodiments, provided compounds have the structure of formula I. In some embodiments, provided compounds comprise ruthenium, and a ligand bonded to ruthenium through a sulfur atom.

Iridium-catalyzed anti-stereocontrolled asymmetric ring opening of azabicyclic alkenes with primary aromatic amines

A novel iridium-catalyzed ring-opening reaction of azabicyclic alkenes with a variety of primary aromatic amines is reported, which afforded the corresponding 1,2-trans-diamine derivatives in high yields (up to 96%) with excellent enantioselectivities (up