28057-18-3Relevant academic research and scientific papers
Synthesis and molecular structure of 1-(2-pyridyloxy)silatrane
Voronkov,Zelbst,Bolgova, Yu. I.,Trofimova,Albanov,Chipanina,Aksamentova,Korlyukov,Antipin, M. Yu.
, p. 2333 - 2338 (2008)
1-(2-Pyridyloxy)silatrane was synthesized by trans-etherification of 1-ethoxysilatrane with 2-hydroxypyridine as well as by the reaction of the latter with tetraethoxysilane and triethanolamine. Its structure was established by the XRD analysis of a single crystal, and in solution using the methods of 1H, 13C, 29Si NMR and IR spectroscopy.
STUDIES ON 1-ARYLOXYSILATRANES, I; KINETICS OF THE HYDROLYSIS OF 1-(2',4',6'-TRIMETHYLPHENOXY)SILATRANE
Lukasiak, J.,Jamrogiewicz, Z.
, p. 19 - 26 (2007/10/02)
A UV spectroscopic method has been developed for studying the kinetics of hydrolysis of 1-(2',4',6'-trimethylphenoxy)silatrane.The effect of temperature and pH on the rate constant of hydrolysis has been determined and a mechanism of the reaction proposed.
