28059-59-8Relevant academic research and scientific papers
Thermal rearrangement of N-benzylanilinium hexafluoroantimonates
Park, Jeongkyu,Shin, Jung-Hyu,Lee, Changjin
, p. 7485 - 7488 (1999)
We prepared p-substituted N-benzylanilinium hexafluoroantimonates, known cationic initiators, and examined their thermal reaction. The thermal reaction produced 2- or 4-benzylanilinium salts as the major products, which resulted from the rearrangement of the benzyl group. The reaction proceeded at lower temperature with higher yield when the substituent in the benzyl group was electron donating.
Thermal reactions of N-Alkyl-2-benzylaniline and N-Alkyl-N′-phenyl-o- phenylenediamine: An unusual route to 2-phenylindole and 2-phenylbenzimidazole
Creencia, Evelyn Cuevas,Taguchi, Kei,Horaguchi, Takaaki
, p. 837 - 843 (2008/09/21)
(Chemical Equation Presented) Thermal cyclization reactions of N-alkyl-2-benzylaniline 1a-d and N-alkyl-N′-phenyl-o-phenylenediamine 2a-b were carried out expecting to get seven-membered heterocyclic compounds. However, the results show that aside from th
