28069-38-7Relevant academic research and scientific papers
Nickel-catalyzed Suzuki Coupling of Cycloalkyl Silyl Peroxides with Boronic Acids
Chen, Lei,Duan, Xin-Hua,Guo, Li-Na,Xu, Pengfei,Yang, Jun-Cheng,Zhang, Jun-Jie
, p. 7515 - 7525 (2020/06/27)
A nickel-catalyzed Suzuki alkyl-aryl coupling of cycloalkyl silyl peroxides with boronic acids is reported. The primary and secondary ketoalkyl electrophiles generated through C-C bond cleavage were amenable, providing rapid access to a variety of distal arylated alkyl ketones. A radical pathway is proposed for this reaction.
Iron-Catalyzed Decarboxylative Olefination of Unstrained Carbon-Carbon Bonds Relying on Alkoxyl Radical Induced Cascade
Gao, Pin,Wu, Hao,Yang, Jun-Cheng,Guo, Li-Na
, p. 7104 - 7108 (2019/09/30)
An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group
Synthesis of hexahydrocyclopenta[c]furans by an intramolecular iron-catalyzed ring expansion reaction
Hilt, Gerhard,Bolze, Patrick,Heitbaum, Maja,Hasse, Katrin,Harms, Klaus,Massa, Werner
, p. 2018 - 2026 (2008/09/17)
The intramolecular iron-catalyzed ring expansion reaction of epoxyalkenes was investigated with a preformed iron(salen) [Fe(Salen)] complex. The formal insertion of the alkene into the epoxide generated hexahydrocyclopenta[c]furan derivatives in moderate to good yields and diastereoselectivities depending on other functional groups present in the starting materials. In addition, oxygen-tethered epoxyalkenes were used for the synthesis of lignan isomers. The scope and limitations of the Fe (Salen)-catalyzed process of the reaction are discussed.
