281-46-9

Basic information

• Product Name: Tricyclo[4.3.1.13,8]undecane
• Synonyms: Tricyclo[4.3.1.13,8]undecane
• CAS NO: 281-46-9
• Molecular Formula: C₁₁H₁₈
• Molecular Weight: 150.26062
• Mol File: 281-46-9.mol
• Article Data: 3

Chemical Properties

• Melting Point: 259-260 °C
• Boiling Point: 210.3±7.0 °C(Predicted)
• Appearance: /
• Density: 0.955±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Tricyclo[4.3.1.13,8]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: Tricyclo[4.3.1.13,8]undecane(281-46-9)
• EPA Substance Registry System: Tricyclo[4.3.1.13,8]undecane(281-46-9)

Safety Data

• Hazardous Substances Data: 281-46-9(Hazardous Substances Data)

Upstream product

• 27011-47-8 homoadamantanyl chloride 
• 56263-64-0 Tricyclo<4.3.1.1^3.8>undecan-3-peroxycarbonsaeure-tert-butylester 
• 79634-92-7 Tricyclo<4.3.1.1^3.8>undecan-1-peroxycarbonsaeure-tert-butylester 
• 157490-72-7 1-(chloromethyl)-2-bromoadamantane 
• 108-98-5 thiophenol 

Downstream Products

• 31061-64-0 Homoadamantan-1-ol 
• 14504-80-4 3-Hydroxyhomoadamantan 
• 3048-63-3 3-Aminohomoadamantan 
• 21898-95-3 1-methoxyhomoadamantane 
• 38584-37-1 1-hydroxy-3-hydroxymethyladamantane 
• 14504-80-4 3-homoadamantanol 
• 24669-56-5 4-homoadamantanone 
• 31061-64-0 1-homoadamantanol 
• 87350-97-8 3,6-homoadamantanediol 
• 14651-42-4 1-(bromomethyl)adamantane 
• 21898-96-4 1-bromohomoadamantane 
• 770-71-8 1-adamantanemethanol 

Relevant articles and documents

1,2-Methanoadamantane: A Molecule with a Twist Bent ? Bond

The reaction of 1-(chloromethyl)-2-bromoadamantane with sodium leads to ring closure to the hitherto unknown 1,2-methanoadamantane (1).Reactivity studies of 1 provide strong evidence for the existence of a twist bent ? bond.

Organic Peroxides, XIV. The Thermal Decomposition of Polycyclic tert-Butyl Bridgehead Peroxycarboxylates

Eleven bridgehead peresters (1, 2, 5 - 8, 10, 12, 14, 18, 21) have been prepared for the first time and the products and the kinetics of their thermal decomposition were investigated.The correlations of all known thermolysis constants of bridgehead peresters with the steric substituent constants φf, with the solvolysis constants of the corresponding bridgehead bromides, as well as with the change in strain enthalpy ΔHsp for hydride abstraction from the bridgehead, as calculated by the procedure of v.R.Schleyer, were analysed.The thermolysis constants of these peresters are mainly determined by the polar effect in the transition state of the perester fragmentation.