28103-68-6Relevant academic research and scientific papers
SIDE PATHS IN THE REACTION OF 1-CHLORO-1-NITROETHANE WITH NITRITE ION
Shugalei, I. V.,Tselinskii, I. V.,Bazanov, A. G.
, p. 2242 - 2246 (2007/10/02)
The main side reactions which accompany the formation of 1,1-dinitroalkanes in the reactions of 1-chloro-1-nitroalkanes with the nitrite ion were studied by UV spectroscopy.The side products are formed as a result of the reaction of nucleophilic particles competing with the nitrite ion (hydroxide ion, 1-halogeno-1-nitroalkane anion, and molecular oxygen) for the chloronitroalkyl radical.The ratios of the rate constants for some of the competing reactions were calculated from the variation in the yield of the main reaction product (1,1-dinitroalkane) in relation to the reaction conditions.
