28114-92-3

Upstream product

• 108-98-5 thiophenol 
• 832-80-4 9-diazofluorenone 
• 1940-57-4 9H-fluoren-9-yl bromide 
• 19552-08-0 9H-fluorene-9-thiol 
• 86-73-7 9H-fluorene 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 81959-13-9 9-(phenylthio)-9-(p-nitrocumyl)fluorene 
• 102001-98-9 9-methyl-9-fluorenyl phenyl thioether 
• 102001-65-0 Phenyl-<9-methyl-fluorenyl-(9)>-sulfon 
• 29800-85-9 9,9'-Bifluoren-9-yl-phenylsulfid 
• 71804-13-2 9-fluorenyl phenyl sulfoxide 
• 116971-93-8 9-(7-cycloheptatrienyl)-9-(phenylthio)fluorene 

Relevant academic research and scientific papers

Strain-Modulated Reactivity: An Acidic Silane

Compounds of main-group elements such as silicon are attractive candidates for green and inexpensive catalysts. For them to compete with state-of-the-art transition-metal complexes, new reactivity modes must be unlocked and controlled, which can be achiev

Base-Promoted Oxidative C(sp3)–S Bond Cross-Coupling of Inactive Fluorenes and Thiols for the Synthesis of 9-Monothiolated Fluorenes

The highly efficient and selective C(sp3)–S bond cross-coupling method for the synthesis of 9-thiolated fluorenes through a direct thiolation at 9-C(sp3)–H of fluorenes with thiols is described. This reaction occurs at ambient conditions and shows good tolerance of functional groups including arylthiols and alkylthiols. A wide range of products is obtained in moderate to good yields. Besides, the reaction of benzothiophenol and fluorine generates unexpected 9-benzylidene-9H-fluorene by eliminating hydrogen sulfide.

Equilibrium Acidities of Nitroalkanes in an Ionic Liquid

The acidity ladder scale in [BMPY][NTf2] was successfully expanded toward the weak acidity region for about five more pK units compared to the previously established one. This allows the acidities of a series of 13 aliphatic and aromatic nitroalkanes to be determined accurately by the UV-vis spectroscopic method. The acidity of nitroalkane in [BMPY][NTf2] covers ～8 pK units and is significantly weaker than those in DMSO and water. The Hammett plot for 4-substituted phenylnitromethanes shows an excellent linearity with a slope of 2.06, which is rather close to that in DMSO but significantly larger than that in water (0.80). The regression analyses reveal that the solvation behavior of [BMPY][NTf2] on the acidic dissociations of C-H acids is similar to that of DMSO.