28123-49-1Relevant academic research and scientific papers
Addition-type oxidation of silylalkene using ozone: An efficient approach for acyloin and its derivatives
Igawa, Kazunobu,Kawasaki, Yuuya,Tomooka, Katsuhiko
, p. 233 - 235 (2011/05/14)
Acyloins are efficiently synthesized in three steps from alkynes via ydrosilylation followed by an addition-type ozone oxidation and hydrogenation. The key intermediate α-silylperoxy ketone is convertible to not only acyloin but also O-silylated acyloin and diketone.
Rhodium-catalyzed homocoupling of (1-Acyloxyvinyl)silanes: Synthesis of 1,3-diene-2,3-diyl diesters and their derivatives
Yue, Yanni,Yamamoto, Hiroki,Yamane, Motoki
scheme or table, p. 2831 - 2835 (2010/03/03)
1,3-Diene-2,3-diyl diesters are synthesized by rhodium-catalyzed homocoupling of (1-acyloxyvinyl)silanes. Double transmetalation between vinylsilane and rhodium intermediate in a single catalytic cycle is the key in this reaction. From the homocoupling pr
REDUCTIVE COUPLING OF S-(2-PYRIDYL) ALIPHATIC THIOATES BY USE OF BIS(1,5-CYCLOOCTADIENE)NICKEL
Onaka, Makoto,Matsuoka, Yoshio,Mukaiyama, Teruaki
, p. 905 - 906 (2007/10/02)
S-(2-Pyridyl) aliphatic thioates are reductively dimerized to give α-diketones and α-hydroxy ketones on treatment with bis(1,5-cyclooctadiene)nickel at 40 deg C.
