28150-13-2Relevant articles and documents
Dinitreno pentaradicals: organic sextet molecules
Mieres-Pérez, Joel,Henkel, Stefan,Mendez-Vega, Enrique,Schleif, Tim,Lohmiller, Thomas,Savitsky, Anton,Sander, Wolfram
, (2017)
A new sextet ground state molecule, the 2,4,6-trichloro-1,3-dinitrenophenoxyl radical, was obtained upon UV photolysis of the corresponding diazido precursor in argon at 5 K. The sextet molecule is formed stepwise with the triplet nitrene, the quartet nitreno radical, and the quintet dinitrene as intermediates that were detected by EPR spectroscopy. IR and UV–Vis measurements only allowed us to observe the main product, the quintet dinitrene. The coupling between the two nitrene centers and the oxygen centered radical in the sextet state results in zero-field splitting (zfs) parameters of |D/hc| = 0.088 cm?1 and |E/hc| = 0.009 cm?1, considerably larger than in previously reported organic sextet molecules. An analogous sextet dinitrene formed by replacing the oxygen centered radical by a carbon centered radical was also studied by EPR spectroscopy, and in this case the zfs parameters |D/hc| = 0.125 cm?1 and |E/hc| = 0.023 cm?1 indicate even larger spin localization. Copyright
Diamination of phenylene dihalides catalyzed by a dicopper complex
Liao, Bei-Sih,Liu, Shiuh-Tzung
experimental part, p. 6653 - 6656 (2012/10/07)
Diamination of phenylene dihalides with aqueous ammonia to give the corresponding phenylenediamines can be achieved by using a dicopper complex [Cu2(bpnp)(OH)(CF3COO)3] (1) (bpnp = 2,7-bis(pyridine-2-yl)-l,8-naphthyridine) as the catalyst in the presence of Bu4NBr and Cs2CO3 in high yields. In addition, 1,3,5-tribromobenzene was converted into benzenetriamine quantitatively under the same conditions. This method offers a new opportunity, particularly simplifying steps and increasing yields, for the preparation of aryl diamines.
Contrast media
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, (2008/06/13)
The invention provides low viscosity iodinated aryl compounds, useful as X-ray contrast agents of formula I wherein n is 0 or 1, and where n is 1 each C6R5moiety may be the same or different; X denotes a bond or a group providing a 1