281654-52-2Relevant academic research and scientific papers
Reactions of β-diketiminatoaluminum hydrides with tert-butyl hydrogenperoxide - Facile formation of dialuminoxanes containing Al-O-Al groups
Uhl, Werner,Jana, Barun
, p. 1101 - 1106 (2009/07/19)
Treatment of diphenyl-β-diketiminatoaluminum dihydride, LAlH2 [1, L = {H5C6-N{double bond, long}C(Me)}2CH] with neopentyl- or trimethylsilylmethyllithium afforded the corresponding alkylderivatives LAlH(R) [R = CH2-SiMe3 (2), CH2-CMe3 (3)] by the precipitation of lithium hydride. Deprotonation of a methyl group instead of salt elimination occurred by the similar reaction of the more basic alkyllithium compound LiC(SiMe3)3. The reactions of the hydrides 1-3 with tert-butyl hydrogenperoxide did not yield the expected peroxo derivatives, instead the dialuminoxanes LAl(R)-O-Al(R)L [R = OCMe3 (5), CH2SiMe3 (6), CH2CMe3 (7)] were isolated in high yields. Their Al-O-Al bridges deviated from linearity and had Al-O-Al bond angles of about 155° on average.
Vinamidine stabilised alanes [1]
Kuhn, Norbert,Fuchs, Stefan,Steimann, Manfred,Kuhn
, p. 1387 - 1392 (2008/10/08)
The alane complexes (C5H7N2R2)AlH2 (2) (R = Me, 1Pr, Ph) are obtained from the vinamidines C5H8N2R2 (1) and Me3N · AlH3 as reactive solids in good yields. Excess hydride reagent affords the formation of perhydrogenated ring systems from which {(C11H24N2)Al2H4} 2 (6) could be prepared in a preparative scale. The X-ray structures of (C5H7N2Me2)AlH2 (2a) and (C5H7N21Pr2)AlH 2 (2b) exhibit the expected near planar ring geometries. In 6, two units of (C11H24N2)Al2H4 (5) are connected via hydrogen bridges to form a central planar Al2H2 core.
