28201-53-8Relevant academic research and scientific papers
Preparation of alpha-hydroxy ketones via carbene-catalyzed umpolung reaction of aldehydes
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Page/Page column 6; 10, (2008/06/13)
The present invention relates to the preparation of α-hydroxy ketones of the general formula I. In particular, the invention relates to novel imidazolinium carboxylate adducts and to a novel process for using catalytic amounts of imidazolium and imidazoli
SYNTHETIC APPROACH TO THE IVERMECTIN BOTTOM HALF USING INTERNAL CYCLOADDUCTS OF N-FURFURYL ACRYLAMIDES: FUNCTIONALITY AND OPTICAL ACTIVITY
Jung, Michael E.,Street, Leslie J.
, p. 45 - 48 (2007/10/02)
The 2-(α-benzyloxyacetyl)furan 2b is converted into the aminal 3b which undergoes internal cycloaddition to give a highly oxidized intermediate 5b in a potential route to ivermectin 1, while the use of (S)-valinol in this sequence permits the ready prepar
