282097-14-7Relevant academic research and scientific papers
Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles
Lautens, Mark,Fagnou, Keith,Taylor, Mark,Rovis, Tomislav
, p. 259 - 270 (2001)
We describe a new rhodium catalysed asymmetric ring opening (ARO) reaction of oxabenzonorbornadienes. This reaction produces a new carbon-oxygen bond via an intermolecular allylic displacement of the bridgehead oxygen with a wide variety of alcohols and p
Hydronaphtalene compounds, prepared by a rhodium catalyzed ring opening reaction in the presence of phosphine ligand
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, (2008/06/13)
The present invention is directed to a procedure for making an enantiomerically enriched compound containing a hydronaphthalene ring structure. The process involves reacting oxabenzonorbornadienes with nucleophiles using rhodium as a catalyst and in the p
