282109-83-5

Basic information

• Product Name: 1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE
• Synonyms: 1,3-BIS(2,6-DI-ISOPROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE;1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE;Bisdiisopropylphenyldihydroimidazoliumtetrafluorobora;1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazoliumtetrafluoroborate,min.95%;1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE, MIN. 95%;SIPr-HBF4, N,Nμ-Bis(2,6-diisopropylphenyl)dihydroimidazolium tetrafluoroborate, 4,5-Dihydro-1,3-bis(2,6-diisopropylphenyl)imidazolium tetrafluoroborate;1,3-BIS(2,6-DIISOPROPYLPHENYL) IMIDAZOLIDINIUM TETRAFLUOROBORATE, 97+%;1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazoliumtetrafluoroborate,95%
• CAS NO: 282109-83-5
• Molecular Formula: C27H39BF4N2
• Molecular Weight: 478.42
• Product Categories: Achiral Nitrogen;NHC;organic amine salt
• Mol File: 282109-83-5.mol
• Article Data: 0

Chemical Properties

• Melting Point: >300
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: White/Powder
• Density: g/cm³
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: 1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE(282109-83-5)
• EPA Substance Registry System: 1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE(282109-83-5)

Safety Data

• Hazard Codes: C
• Statements: 20-34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 1759 8/PG 2
• WGK Germany: 3
• TSCA: No
• Hazardous Substances Data: 282109-83-5(Hazardous Substances Data)

Usage

Reaction

In-situ deprotonation leads to metal carbene species which acts as a catalyst in a variety of C-C and C-N bond forming reactions. Ligand used in the nickel or palladium-catalyzed coupling of aryl chlorides and amines. Ligand used for the palladium-catalyzed arylation of esters and amides. Ligand used for the palladium-catalyzed intermolecular amination of Csp3–H Bonds. Ligand used for the nickel-catalyzed hydrogenation of olefins.

Chemical Properties

White powder

InChI:InChI=1/C27H39N2.BF4/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;2-1(3,4)5/h9-14,17-21H,15-16H2,1-8H3;/q+1;-1