283172-40-7Relevant academic research and scientific papers
Fully reversible cyclic dimerization of diphosphanylketenimines promoted by intramolecular C-H···N hydrogen bonds
Ruiz, Javier,Marquinez, Fernando,Riera, Victor,Vivanco, Marilin,Garcia-Granda, Santiago,Diaz, M. Rosario
, p. 1821 - 1823 (2000)
Just by crystallization at room temperature the diphosphanylketenimine 1 is transformed into the unsymmetrical dimer 2 through a novel [2+3] cycloaddition reaction; a phosphanyl substituent is involved in the annelation process. This dimerization is fully reversible and appears to be promoted by intramolecular CH···N hydrogen bonds.
