2835-33-8

Basic information

• Product Name: 3-(2-PYRIDYL)-1-PROPENE
• Synonyms: 3-(2-PYRIDYL)-1-PROPENE
• CAS NO: 2835-33-8
• Molecular Formula: C8H9N
• Molecular Weight: 119.16
• Mol File: 2835-33-8.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 212.46°C (rough estimate)
• Flash Point: 50.1°C
• Appearance: /
• Density: 0.9590
• Vapor Pressure: 0.767mmHg at 25°C
• Refractive Index: 1.5330 (estimate)
• CAS DataBase Reference: 3-(2-PYRIDYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-PYRIDYL)-1-PROPENE(2835-33-8)
• EPA Substance Registry System: 3-(2-PYRIDYL)-1-PROPENE(2835-33-8)

Safety Data

• Hazardous Substances Data: 2835-33-8(Hazardous Substances Data)

Usage

General Description

3-(2-pyridyl)-1-propene, also known as 2-pyridyl propene or 3-(2-pyridyl)prop-1-ene, is a chemical compound with the molecular formula C9H9N. It is an unsaturated compound with a pyridine ring and a propene chain. This chemical is used as an intermediate in the synthesis of pharmaceuticals, agrochemicals, and organic compounds. It is also used in the manufacturing of various consumer products, including fragrances and flavorings. 3-(2-pyridyl)-1-propene is flammable and should be handled with care due to its potential for combustion and toxic effects.

InChI:InChI=1/C8H9N/c1-2-5-8-6-3-4-7-9-8/h2-4,6-7H,1,5H2

Upstream product

• 694-59-7 pyridine N-oxide 
• 106-95-6 allyl bromide 
• 109-09-1 2-chloropyridine 
• 24850-33-7 allyltributylstanane 
• 2637-34-5 2-Sulfanylpyridine 
• 94161-81-6 2-allyl-1-(ethoxycarbonyl)-1,2-dihydropyridine 
• 18925-10-5 allylzinc bromide 
• 89818-47-3 (+/-)-2-(allylsulfinyl)pyridine 
• 111480-81-0 Pyridyl-2-neopentylsulfonate 
• 1730-25-2 allylmagnesium bromide 
• 109-04-6 2-bromo-pyridine 

Downstream Products

• 581-50-0 2,3'-bipyridine 

Relevant articles and documents

Highly active and recyclable silica gel-supported palladium catalyst for mild cross-coupling reactions of unactivated heteroaryl chlorides

Silica gel-supported β-ketoiminatophosphane-Pd complex (Pd@SiO 2) was shown to be a highly active and long-lived catalyst for aqueous Suzuki, Stille and Sonogashira coupling reactions of heteroaryl chlorides. A wide range of heteroaryl chlorides could be efficiently coupled with different nucleophilic partners in the presence of only 0.5 mol% catalyst and under mild conditions. This is one of the most powerful heterogeneous catalysts for the couplings of diverse heteroaryl chlorides. Furthermore, the catalyst could be reused with almost consistent activity. The Royal Society of Chemistry 2010.

Ligand coupling reactions of 2-pyridyl, 4-pyridyl and 2-pyrimidyl sulfoxides with grignard reagents

The ligand coupling reaction was extended to 3-and 4-pyridyl sulfoxides as well as the 2-pyrimidyl moiety with Grignard reagents. It was found that both 4-pyridyl and 2-pyrimidyl sulfoxides nicely underwent the ligand coupling reactions, but 3-pyridyl sulfoxide underwent ligand exchange.

Synthese regioselective par voie organometallique de pyridines, 4-picolines et 3,5-lutidines substituees en 2 par un groupe insature et/ou fonctionnel

A regioselective one-pot synthesis of 2-substituted pyridine derivatives from N-alkoxycarboxylpyridinium salts and α-unsaturated organozinc compounds is described.Similarly, functional alkynyl organomagnesium compounds lead to 2-alkynyl-ω-functional pyridines, from which (E)-2-alkenyl or 2-alkyl-ω-functional pyridines can be obtained by partial or complete reduction.