28352-34-3Relevant academic research and scientific papers
Stereoselective Epoxidations and Electrophilic Additions to Partial Ergot Alkaloids and Conformationally-Fixed Styrenes. Experimental and Theoretical Modeling Evidence for the Importance of Torsional Steering as a Stereocontrol Element
Martinelli, Michael J.,Peterson, Barry C.,Khau, Vien V.,Hutchison, Darrell R.,Leanna, M. Robert,et al.
, p. 2204 - 2210 (2007/10/02)
Partial ergot alkaloid substrates and related conformationally-fixed styrenes undergo epoxidation, osmium tetraoxide dihydroxylation, and hydrobromination with a level of stereoselectivity which cannot be explained by steric control but is consistent with
Conformational Effects in the Hydrolyses of Rigid Benzylic Epoxides: Implications for Diol Epoxides of Polycyclic Hydrocarbons
Sayer, J. M.,Yagi, H.,Silverton, J. V.,Friedman, S. L.,Whalen, D. L.,Jerina, D. M.
, p. 1972 - 1978 (2007/10/02)
The two conformationally rigid, diastereomeric 9,10-oxides derived from trans-1,2,3,4,4a,10a-hexahydrophenanthrene have been synthesized, and their relative stereochemistries have been verified by X-ray structure determination of the acetate of the bromoh
