28352-34-3Relevant articles and documents
Stereoselective Epoxidations and Electrophilic Additions to Partial Ergot Alkaloids and Conformationally-Fixed Styrenes. Experimental and Theoretical Modeling Evidence for the Importance of Torsional Steering as a Stereocontrol Element
Martinelli, Michael J.,Peterson, Barry C.,Khau, Vien V.,Hutchison, Darrell R.,Leanna, M. Robert,et al.
, p. 2204 - 2210 (2007/10/02)
Partial ergot alkaloid substrates and related conformationally-fixed styrenes undergo epoxidation, osmium tetraoxide dihydroxylation, and hydrobromination with a level of stereoselectivity which cannot be explained by steric control but is consistent with