284022-81-7Relevant academic research and scientific papers
Generation of functionalized aryl and heteroaryl aluminum reagents by halogen-lithium exchange
Klatt, Thomas,Groll, Klaus,Knochel, Paul
supporting information, p. 6953 - 6955 (2013/09/02)
Various functionalized aryl and heteroaryl aluminum reagents were obtained by performing I-Li or Br-Li exchange reactions with the corresponding unsaturated organic halides in the presence of i-Bu2AlCl. By means of an appropriate catalyst, the
Copper catalyzed conjugate addition of highly functionalized arylmagnesium compounds to enones
Varchi, Greta,Ricci, Alfredo,Cahiez, Gérard,Knochel, Paul
, p. 2727 - 2731 (2007/10/03)
Highly functionalized arylmagnesium bromides are readily prepared by an iodine-magnesium exchange reaction. In the presence of catalytic amounts of copper(I) salts and chlorotrimethylsilane, they add to various enones leading to the conjugate addition pro
