2844-89-5

Basic information

• Product Name: CYCLOHEXYLDICHLOROPHOSPHINE
• Synonyms: CYCLOHEXYLPHOSPHONOUS DICHLORIDE;CYCLOHEXYLDICHLOROPHOSPHINE;Cyclohexyl-dichlorophosphin;Cyclohexyldichlorophosphine,98%;Cyclohexylphosphorus dichloride;Dichlorocyclohexylphosphin;dichloro(cyclohexyl)phosphane
• CAS NO: 2844-89-5
• Molecular Formula: C₆H₁₁Cl₂P
• Molecular Weight: 185.03
• Product Categories: Chlorophosphines;Phosphorus Precursors;Catalysis and Inorganic Chemistry;Phosphorus Compounds;organophosphine halide
• Mol File: 2844-89-5.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 89-99°C 17mm
• Flash Point: 67 °C
• Appearance: colorless/liquid
• Density: 1,2 g/cm3
• Vapor Pressure: 0.231mmHg at 25°C
• Refractive Index: n20/D 1.528
• Sensitive: air sensitive, moisture sensitiv
• CAS DataBase Reference: CYCLOHEXYLDICHLOROPHOSPHINE(CAS DataBase Reference)
• NIST Chemistry Reference: CYCLOHEXYLDICHLOROPHOSPHINE(2844-89-5)
• EPA Substance Registry System: CYCLOHEXYLDICHLOROPHOSPHINE(2844-89-5)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: 1760
• WGK Germany: 3
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 2844-89-5(Hazardous Substances Data)

Usage

General Description

CYCLOHEXYLDICHLOROPHOSPHINE is a chemical compound with the formula C6H11PCl2. It is a white crystalline solid with a molecular weight of 180.51 g/mol. CYCLOHEXYLDICHLOROPHOSPHINE is commonly used as a reagent in organic synthesis reactions, particularly in the preparation of phosphine ligands for catalysis. It is a versatile compound that can undergo various chemical transformations, including substitution and addition reactions. CYCLOHEXYLDICHLOROPHOSPHINE is also known for its use in the production of agrochemicals, pharmaceuticals, and other industrial chemicals. Despite its usefulness, it is important to handle CYCLOHEXYLDICHLOROPHOSPHINE with care, as it is a hazardous chemical that can cause irritation to the skin, eyes, and respiratory system upon exposure.

InChI:InChI=1/C6H11Cl2P/c7-9(8)6-4-2-1-3-5-6/h6H,1-5H2

Upstream product

• 110-82-7 cyclohexane 
• 822-68-4 cyclohexylphosphine 
• 542-18-7 cyclohexyl chloride 
• 931-51-1 cyclohexylmagnesiumchloride 
• 70530-88-0 Chlor-diethylamino-cyclohexyl-phosphan 

Downstream Products

• 70530-88-0 Chlor-diethylamino-cyclohexyl-phosphan 
• 3040-71-9 tetracyclohexylcyclotetraphosphine 
• 13689-16-2 diphenyl cyclohexylphosphonate 
• 134152-60-6 Mo(P(C₆H₅)2)(PC₆H₁₁)(CO)2(C₅H₅) 
• 134152-61-7 (η(5)-C5H5)W(CO)2(CyPPPh2) 
• 134152-59-3 Cr(P(C₆H₅)2)(PC₆H₁₁)(CO)2(C₅H₅) 
• 95608-75-6 (C₆H₁₁)Cl₂PMn(C₅H₅)(CO)2 
• 97913-31-0 (dichloro-cyclohexyl-phosphane)tetracarbonyliron 
• 1082074-41-6 [Ph₃P-PCy(Cl)][OTf] 
• 1082074-43-8 [Me₃P-PCy(Cl)][OTf] 

Relevant articles and documents

Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis

Phosphines are important ligands in homogenous catalysis and have been crucial for many advances, such as in cross-coupling, hydrofunctionalization, or hydrogenation reactions. Herein we report the synthesis and application of a novel class of phosphines bearing ylide substituents. These phosphines are easily accessible via different synthetic routes from commercially available starting materials. Owing to the extra donation from the ylide group to the phosphorus center the ligands are unusually electron-rich and can thus function as strong electron donors. The donor capacity surpasses that of commonly used phosphines and carbenes and can easily be tuned by changing the substitution pattern at the ylidic carbon atom. The huge potential of ylide-functionalized phosphines in catalysis is demonstrated by their use in gold catalysis. Excellent performance at low catalyst loadings under mild reaction conditions is thus seen in different types of transformations.

Synthesis, structure, magnetism and nuclease activity of tetranuclear copper(ii) phosphonates containing ancillary 2,2′-bipyridine or 1,10-phenanthroline ligands

The reaction of cyclohexylphosphonic acid (C6H 11PO3H2), anhydrous CuCl2 and 2,2′-bipyridine (bpy) in the presence of triethylamine followed by a metathesis reaction with KNO3 afforded [Cu

Synthesis and properties of new fused bicyclic compounds containing P-B- S linkages

New bicyclic compounds, (P-B)-12-phenyl-12H-dibenzo[d,g]-[ 1,3,6,2]dithiaphosphaborocine (3a) and (P-B)-12-cyclohexyl-12H-dibenzo [d,g][1,3,6,2]dithiaphosphaborocine (3b), were synthesized by the reaction of phenyl- and cyclohexylbis(2-mercaptophenyl)phos