284476-10-4Relevant articles and documents
The syntheses, 31P{1H} NMR spectra and cyclic voltammetry of trinuclear [Pd2M(μ3-Se)2(dppe)3] 2+ {M = Ni or Pt; dppe = 1,2-bis(diphenylphoshino)ethane}
Matsumoto, Keiji,Kotoku, Naho,Shizuka, Takeshi,Tanaka, Rika,Okeya, Seichi
, p. 167 - 170 (2001)
Trinuclear [Pd2M(μ3-Se)2(dppe)3] 2+ (M = Ni or Pt) and pentanuclear [M′{Pd2(μ3-Se)2(dppe)2} 2]2+ (M′ = Ni, Pd or Pt) clusters have been prepared using a metalloligand [Pd2(μ-Se)2(dppe)2] and characterized by 31P{1H} NMR spectroscopy and cyclic voltammetry. [Pd2Ni(μ3-Se)2(dppe)3] 2+ gives two chemically reversible couples, [Pd2Pt(μ3-Se)2(dppe)3] 2+ exhibits one chemically reversible couple and pentanuclear clusters show three couples in each cyclic voltammogram of the reduction process at 255 K. The redox behavior of the clusters is discussed.
