284493-65-8

Usage

Chemical Properties

white powder

InChI:InChI=1/C14H18ClNO4/c1-14(2,3)20-13(19)16-11(8-12(17)18)9-5-4-6-10(15)7-9/h4-7,11H,8H2,1-3H3,(H,16,19)(H,17,18)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 24424-99-5 di-tert-butyl dicarbonate 
• 19947-39-8 3-amino-3-(4-chlorophenyl)propionic acid 
• 271600-23-8 [(R)-1-(4-Chloro-phenyl)-3-oxo-3-((1R,2R,4R)-1,7,7-trimethyl-2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-propyl]-carbamic acid benzyl ester 

Downstream Products

• 1449584-15-9 tert-butyl 2-(4-chlorophenyl)-4,6-dioxopiperidine-1-carboxylate 

Relevant academic research and scientific papers

Annulation of 2H-pyran onto 1-Oxa- or 1-azacyclohexane-2,4-diones and their analogues via sequential condensation with -substituted enals and 6π-electrocyclization

2H-Pyrans are constructed on a 1-oxa- or 1-azacyclohexane-2,4-dione core via Knoevenagel condensation with enals followed by 6π.electrocyclization, which are readily catalyzed with ethylenediammonium diacetate. This formal [3 + 3] strategy constitutes CO

α-Oxymethyl ketone enolates for the asymmetric Mannich reaction. From acetylene and N-alkoxycarbonylimines to β-amino acids

The insufficient diastereoselectivity and generality, which are the main problems of the 'acetate' aza - aldol reaction, can now be addressed through the reaction of the lithium enolate of endo-O-trimethylsilyl acetyl isoborneol with various N[(p-tolylsul