284684-50-0

Upstream product

• 79454-85-6 [bis(trimethylsilyl)methylene]chlorophosphane 
• 14040-11-0 tungsten hexacarbonyl 

Downstream Products

• 1192114-98-9 W(CO)5(PIClCH(Si(CH₃)3)2) 
• 1192115-00-6 W(CO)5(PCl(CH(Si(CH₃)3)2)CHCIC₆H₅) 
• 1192115-01-7 W(CO)5(P(CCC₆H₅)2CI(Si(CH₃)3)2) 
• 16872-10-9 1-methyl-o-carborane 
• 1254976-54-9 [tungsten(pentacarbonyl)P(C₆H₄CPh₂)(CH(SiMe₃)2)] 
• 1271741-48-0 [W(CO)5(HP(C(O)C₆H₅)CH(Si(CH₃)3)2)] 
• 1271741-46-8 [W(CO)5(CH₃P(C(O)C₆H₅)CH(Si(CH₃)3)2)] 
• 1271741-45-7 [W(CO)5(C₆H₅C(OC(O)C₆H₅)PCH(Si(CH₃)3)2)] 
• 1271741-38-8 [W(CO)5(C₆H₅C(O)P(CH(Si(CH₃)3)2)Cl)] 
• 1374585-28-0 W(CO)5PH(CH(Si(CH₃)3)2)(NH(C₃H₇)) 
• 1374585-27-9 W(CO)5PH(CH(Si(CH₃)3)2)(N(C₆H₅)2) 
• 1416967-49-1 [W(CO)5(PH(CH(SiMe₃)2)(O-2,6-Me₂C₆H₃))] 
• 1416967-40-2 [W(CO)5(PMe(CH(SiMe₃)2)(OPh)] 
• 1416967-42-4 [W(CO)5(PCl(CH(SiMe₃)2)(OPh))] 

Relevant academic research and scientific papers

Chemistry of 2H-azaphosphirene complexes, 20 - Study on the ring formation of 2H-azaphosphirene complexes using sterically demanding C-2,4,6- trialkylphenyl-substituted aminocarbene tungsten complexes - Detection of a key intermediate

The synthesis of C-2,4,6-trialkylphenyl-substituted ethoxy- and aminocarbene tungsten complexes 1a-c (R = Me, iPr and tBu) and 2a,b (R = Me, iPr) and the reaction of 2a,b with [bis(trimethylsilyl)methylene]chlorophosphane (3) in the presence of triethylam

Synthesis and spectroscopic data of para-substituted (3-phenyl-2H-azaphosphirene)tungsten complexes

High-yield synthesis of para-substituted pentacarbonyl(3-phenyl-2H-azaphosphirene)tungsten complexes is reported, using a multi-step rearrangement reaction. Spectroscopic and mass-spectrometric data of these heterocyclic complexes are discussed; the 31P-NMR-chemical shifts clearly reflect the electronic influence of the para-phenyl substituents and the correlation with Hammett σp-constants is almost linear.