28495-28-5Relevant academic research and scientific papers
Preparation of 1-Alkoxy-1,3-cyclohexadienes via Iron Complexation/Decomplexation
Rennels, Roger A.,McClusky, John V.
, p. 651 - 656 (2007/10/03)
A synthetic method for the preparation of 1-alkoxy-1,3-cyclohexadienes is presented. Iron complexation/decomplexation is used to produce and purify the desired compound without contamination of isomeric by products.
Thermodynamics of Vinyl Ethers. 31. Isomer Equilibria in Some Six- and Seven-Membered Cyclic Dienes
Taskinen, Esko,Nummelin, Kari
, p. 4844 - 4847 (2007/10/02)
The relative thermodynamic stabilities of 1,3-cyclohexadiene and 1,4-cyclohexadiene, together with a number of their alkoxy and other derivatives and some related seven-membered cyclic dienes, have been determined by chemical equilibration in Me2SO and cyclohexane solution at various temperatures.The values of the thermodynamic parameters ΣG, ΔH, and ΔS for the isomerization processes involved are discussed and show clearly that the apparently conjugated diene system of 1,3-cyclohexadiene is devoid of conjugation, contrary to that of 1,3-cycloheptadiene.
