28495-72-9

Basic information

• Product Name: 3-Pentanone p-Toluenesulfonylhydrazone
• Synonyms: 3-Pentanone p-Toluenesulfonylhydrazone;3-Pentanone Tosylhydrazone;3-Pentanone p-Toluenesulfonylhydrazone
• CAS NO: 28495-72-9
• Molecular Formula: C₁₂H₁₈N₂O₂S
• Molecular Weight: 254.35
• Mol File: 28495-72-9.mol
• Article Data: 9

Chemical Properties

• Melting Point: 103 °C
• Boiling Point: 377°Cat760mmHg
• Flash Point: 181.8°C
• Appearance: /
• Density: 1.13g/cm³
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 3-Pentanone p-Toluenesulfonylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanone p-Toluenesulfonylhydrazone(28495-72-9)
• EPA Substance Registry System: 3-Pentanone p-Toluenesulfonylhydrazone(28495-72-9)

Safety Data

• Hazardous Substances Data: 28495-72-9(Hazardous Substances Data)

Usage

General Description

3-Pentanone p-Toluenesulfonylhydrazone is an organic compound that is used as a reagent in chemical reactions. It is commonly utilized in the synthesis of various compounds, as it can undergo reactions such as reduction, oxidation, and acylation. This chemical is known for its ability to form stable crystalline complexes, making it a valuable tool in analytical and preparative chemistry. Additionally, it has been utilized in the determination of carbonyl compounds in mixtures, due to its selective reaction with carbonyl groups. Overall, 3-Pentanone p-Toluenesulfonylhydrazone plays a versatile role in organic chemistry and is an important reagent in many chemical processes.

Upstream product

• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 96-22-0 pentan-3-one 

Downstream Products

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• 1094374-92-1 1-(4-chlorophenyl)-2-ethylbutan-1-one 
• 39178-63-7 2-(pentan-3-yl)benzofuran 
• 1393683-26-5 1-(3-ethylpent-2-en-1-yl)-4-methoxybenzene 
• 1338091-93-2 N-allyl-4-methyl-N'-(pentan-3-ylidene)benzenesulfonohydrazide 
• 18421-23-3 (E)-1-methoxy-4-(pent-2-en-3-yl)benzene 
• 33143-15-6 (2-ethylbut-1-en-1-yl)benzene 
• 101541-94-0 5,8b-Dihydro-8b-methyl-7-phenyl-6H-1,2,3-thiadiazolo<5,4-c><1,2,4>triazolo<1,2-a>pyridazin-6,8(7H)-dion 

Relevant articles and documents

Synthetic Routes for Heteroatom-Containing Alkylated/Arylated Polycyclic Aromatic Hydrocarbons

Synthetic routes for heteroatom-containing polycyclic aromatic hydrocarbons (H-PAHs) with alkyl and aryl substitution are demonstrated. Three H-PAHs, including heteroatom-containing rubicenes (H-rubicenes), angular-benzothiophenes (ABTs), and indenothioph

Zinc-promoted cyclization of tosylhydrazones and 2-(dimethylamino)malononitrile: An efficient strategy for the synthesis of substituted 1-tosyl-1: H -pyrazoles

A Zn(OTf)2-promoted cyclization reaction of tosylhydrazones with 2-(dimethylamino)malononitrile has been successfully developed providing an efficient strategy for the synthesis of substituted 1-tosyl-1H-pyrazoles.

Csp2-N bond formation via ligand-free Pd-catalyzed oxidative coupling reaction of N -tosylhydrazones and indole derivatives

In a fresh approach to the synthesis of N-vinylazoles, a ligand-free palladium catalytic system was found to promote the Csp2-N bond-forming reaction utilizing N-tosylhydrazones and N-H azoles. This process shows functional group tolerance; di-, tri-, and tetrasubstituted N-vinylazoles were obtained in high yields. Under the optimized conditions, the reaction proceeds with high stereoselectivity depending on the nature of the coupling partners.