285133-45-1

Basic information

• Product Name: (Z)-2-bromo-2-(5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone
• Synonyms: (Z)-2-bromo-2-(5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone
• CAS NO: 285133-45-1
• Molecular Weight: 384.25
• Mol File: 285133-45-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (Z)-2-bromo-2-(5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-bromo-2-(5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone(285133-45-1)
• EPA Substance Registry System: (Z)-2-bromo-2-(5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone(285133-45-1)

Safety Data

• Hazardous Substances Data: 285133-45-1(Hazardous Substances Data)

Upstream product

• 204690-23-3 (Z)-(5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone 

Downstream Products

• 235423-21-9 (2E,5Z)-(5-ethoxycarbonylmethylidene-4-oxothiazolidine-2-ylidene)-1-phenylethanone 

Relevant articles and documents

Transformations of 2-alkylidene-4-oxothiazolidine vinyl bromides initiated by bromophilic attack of neutral and anionic nucleophiles

Vinyl bromides derived from 2-alkylidene-4-oxothiazolidines represent a class of vinyl halides, which readily undergo a bromophilic attack by a range of nucleophiles. With Ph3P, AcS-, CN-, I -, F-, Ac

Regioselective synthesis of new 5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene bromides and rearrangement reaction thereof

(Z)-5-Substituted-2-alkylidene-4-oxothiazolidine derivatives 2a-c were regioselectively brominated to afford the new, synthetically useful vinyl bromides 3a-c. They undergo novel rearrangement reaction to provide 4-oxothiazolidine derivatives 5a-c containing two fully conjugated exocyclic double bonds. Extremely clean and efficient derivatization of 2a-c to 5a-c was also achieved by a one-pot three-step sequence under mild experimental conditions without isolation of vinyl bromides 3a-c. Thieme Stuttgart.