28519-17-7Relevant academic research and scientific papers
The thionophosphate-thiolophosphate photoisomerization proceeds predominantly through a non-chain radical pathway. Synthetically viable benzylation of tetrahydrofuran, propan-2-ol and olefins
Yadav, Veejendra K.,Balamurugan, Rengarajan,Parvez, Masood,Yamdagni, Raghav
, p. 323 - 332 (2007/10/03)
The photoirradiation of thionophosphates, ROP(S)(OEt)2, derived from benzyl and vinylogously benzyl alcohols in CH3CN, with a Hanovia medium-pressure mercury lamp in a quartz vessel leads to the formation of the corresponding thiolophosphates, RSP(O)(OEt)2, through a non-chain radical pathway. This behavior of thionophosphates is unlike that of the related phosphates, which react through ionic dissociation-recombination processes. When the irradiation is conducted in solvents such as PriOH, THF and toluene, benzylation of these solvents takes place in synthetically respectable yields. Irradiation of thionophosphates in CH3CN leads to a convenient allylic benzylation of olefins.
A New, Efficient Synthesis of Thioloesters
Nowicki, Tomasz,Markowska, Anna,Kielbasinski, Piotr,Mikolajczyk, Marian
, p. 305 - 308 (2007/10/02)
The reaction between phosphorothioic and thiocarboxylic acids and O-alkyl-N,N-dicyclohexylisoureas has been found to give the corresponding phosphorothiolates and thiolocarboxylates in high yields (65-95percent), providing a new method for the thiophosphorylation and thiocarboxylation of alcohols.
HYDROLYSIS OF CYANOHYDRIN ESTERS
Dixon, Brian G.,Au, Andrew T.
, p. 1123 - 1126 (2007/10/02)
The kinetics of the base hydrolyses of a series of α-cyano thiophosphate esters are presented.A classic Hammett sigma-rho analysis showed these hydrolyses to be bimolecular in nature.
