28541-77-7

Basic information

• Product Name: 4-Bromophenyl beta-D-mannopyranoside
• Synonyms: a-D-Mannopyranoside, 4-bromophenyl
• CAS NO: 28541-77-7
• Molecular Formula: C₁₂H₁₅BrO₆
• Molecular Weight: 335.1479
• Mol File: 28541-77-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 528.688°C at 760 mmHg
• Flash Point: 273.541°C
• Density: 1.739g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.643
• CAS DataBase Reference: 4-Bromophenyl beta-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Bromophenyl beta-D-mannopyranoside(28541-77-7)
• EPA Substance Registry System: 4-Bromophenyl beta-D-mannopyranoside(28541-77-7)

Safety Data

• Hazardous Substances Data: 28541-77-7(Hazardous Substances Data)

Upstream product

• 530-26-7 D-Mannose 
• 83-87-4 D-Mannose pentaacetate 
• 28619-28-5 4-bromophenyl 2,3,4,6-tetra-O-acetyl-α-D-mannopyranoside 
• 3046-26-2 p-bromophenol, potassium salt 
• 53958-21-7 4,6-di-O-acetyl-2,3-O-carbonyl-α-D-mannopyranosyl bromide 
• 2823-44-1 2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl fluoride 
• 187269-63-2 2,3,4,6-tetra-O-pivaloyl-α-D-mannopyranosyl fluoride 
• 2713-54-4 α-D-mannopyranosyl fluoride 
• 66888-27-5 penta-O-acetyl-D-mannose 
• 106-41-2 4-bromo-phenol 
• 243120-93-6 4-bromophenyl tetra-O-pivaloyl-α-D-mannopyranoside 
• 120489-17-0 Acetic acid (3aS,4R,6R,7R,7aS)-6-acetoxymethyl-4-(4-bromo-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester 

Relevant articles and documents

Preparation and characterization of glycopolymers with biphenyl spacers: Via Suzuki coupling reaction

Poly(vinylbiphenyl)s bearing glycoside ligands at the side chains were prepared using the Suzuku coupling reaction. Effects of glycoside reactant concentration, halide species, glycoside species, and catalyst species on the incorporation of glycoside ligand into the polymer were investigated. The obtained glycopolymers exhibited specific binding to proteins corresponding to the glycoside ligands. In addition, the biphenyl spacers formed by the Suzuki coupling reaction in the glycopolymer were fluorescent, whereas the polymer precursor was not.

Stereospecific α-D-mannosylation

The stereospecific formation of α-D-mannosyl glycosidic linkages has been achieved in high yield using tetra-O-pivaloyl-α-D-mannopyranosyl fluoride and boron trifluoride diethyl etherate in dichloromethane. Examples of the α-D-mannosylation of primary, secondary, benzylic and phenolic hydroxyl groups are described. Copyright (C) 1999 Elsevier Science Ltd.