286014-44-6

Basic information

• Product Name: 3-methyl-1-(2,4,6-trimethylphenyl)-1H-imidazol-3-ium iodide
• Synonyms: 3-methyl-1-(2,4,6-trimethylphenyl)-1H-imidazol-3-ium iodide
• CAS NO: 286014-44-6
• Molecular Weight: 328.196
• Mol File: 286014-44-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-methyl-1-(2,4,6-trimethylphenyl)-1H-imidazol-3-ium iodide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-1-(2,4,6-trimethylphenyl)-1H-imidazol-3-ium iodide(286014-44-6)
• EPA Substance Registry System: 3-methyl-1-(2,4,6-trimethylphenyl)-1H-imidazol-3-ium iodide(286014-44-6)

Safety Data

• Hazardous Substances Data: 286014-44-6(Hazardous Substances Data)

Upstream product

• 25364-44-7 N-(2,4,6-trimethylphenyl)imidazole 
• 74-88-4 methyl iodide 

Downstream Products

• 947519-25-7 1,3-dihydro-1-mesityl-3-methyl-2H-imidazol-2-ylidene 
• 1197155-00-2 1-mesityl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide 
• 1308849-61-7 1-(2,4,6-trimethylphenyl)-3-methylimidazolium-2-carboxylate 
• 916171-30-7 Fe(C₅H₅)(CO)2(C₃H₂N₂(CH₃)(C₆H₂(CH₃)3))⁽¹⁺⁾*I^(1-)=[(C₅H₅)Fe(CO)2(C₃H₂N₂(CH₃)(C₆H₂(CH₃)3))]I 

Relevant articles and documents

Simple and reactive Ir(i) N-heterocyclic carbene complexes for alkyne activation

Two simple unsymmetrical monometallic Ir(i) complexes with an N-heterocyclic carbene ligand and an analogous bimetallic Ir(i) complex were synthesised. These complexes were found to be extremely active catalysts for a range of C-X (X = N or O) and Si-N bond forming reactions involving alkyne and imine activation for dihydroalkoxylation, hydroamination and hydrosilylation reactions. These catalysts exhibited reaction rates far exceeding those of other Rh(i) and Ir(i) complexes previously reported. In addition, a small change to the ligand design (phenyl vs. mesityl) substantially affected both the reactivity and product selectivity of the catalyst. The Ir(i) complex bearing a mesitylene wingtip provided unprecedented regioselectivity in the dihydroalkoxylation reaction and a new kinetic product from the typical hydrosilylation protocol of 2-benyzlpyrroline to produce an N-silylaminoalkene. Our mechanistic studies indicated that this transformation proceeded via a dehydrogenative coupling mechanism.

Tunable Aryl Alkyl Ionic Liquids with Weakly Coordinating Tetrakis((1,1,1,3,3,3-hexafluoropropan-2-yl)oxy)borate [B(hfip)4] Anions

Weakly coordinating borate or aluminate anions have recently been shown to yield interesting properties of the resulting ionic liquids (ILs). The same is true for large phenyl-substituted imidazolium cations, which can be tuned by the choice, position, or

Gold(I)-catalyzed cyclizations of 1,6-enynes: Alkoxycyclizations and exol endo skeletal rearrangements

Gold(1) complexes are the most active catalysts for alkoxy- or hydroxycyclization and for skeletal rearrangement reactions of 1,6-enynes. Intramolecular alkoxycyclizations also proceed efficiently in the presence of gold(I) catalysts. The first examples o