286376-18-9

Basic information

• Product Name: Bis(2-{[(trimethylsilyl)oxy]methyl}phenyl)acetylene
• Synonyms: Bis(2-{[(trimethylsilyl)oxy]methyl}phenyl)acetylene
• CAS NO: 286376-18-9
• Molecular Weight: 382.65
• Mol File: 286376-18-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bis(2-{[(trimethylsilyl)oxy]methyl}phenyl)acetylene(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(2-{[(trimethylsilyl)oxy]methyl}phenyl)acetylene(286376-18-9)
• EPA Substance Registry System: Bis(2-{[(trimethylsilyl)oxy]methyl}phenyl)acetylene(286376-18-9)

Safety Data

• Hazardous Substances Data: 286376-18-9(Hazardous Substances Data)

Upstream product

• 18887-51-9 2,2'-Bis-acetoxymethyl-diphenylacetylen 
• 38002-45-8 3-bromo-1-(trimethylsilyl)-1-propyne 
• 18887-49-5 2-[2-(2-hydroxymethylphenyl)-1-ethynyl]phenylmethanol 

Relevant articles and documents

Synthesis of aromatic triynes as precursors to helicene derivatives

A general and versatile synthetic approach to a broad series of aromatic triynes as precursors to helicene derivatives has been developed. Employing a set of simple tools, triynes comprising the (phenylethynyl)benzene, 1-(phenylethynyl)naphthalene, and 1-(1-naphthylethynyl)-naphthalene moiety have been prepared in good to excellent yields throughout the whole reaction sequence. The methodology allows constructing various types of a junction between the central diarylacetylene moiety and the attached acetylene units to get the target triynes of general formula R-C≡C-CH2-X-CH2-Ar-C≡C-Ar-CH 2-X-CH2-C≡C-R or R-C≡C-CH2CH2-Ar-C=C-Ar-CH2CH 2-C≡C-R (R = H, CH3, TMS, or TIPS; X = O, NTs, or C(CO2CH3)2; Ar/Ar = 2-phenylene or 2-naphthylene).