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CAS

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286385-08-8

bis(triphenylphosphoranylidene)ammonium tetrahedro-nonacarbonyl(hydrido)(μ3-bis(diphenylphosphino)methane)tetrairidate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 286385-08-8 Structure

  • Basic information

    1. Product Name: bis(triphenylphosphoranylidene)ammonium tetrahedro-nonacarbonyl(hydrido)(μ3-bis(diphenylphosphino)methane)tetrairidate
    2. Synonyms:
    3. CAS NO:286385-08-8
    4. Molecular Formula:
    5. Molecular Weight: 1944.97
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 286385-08-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: bis(triphenylphosphoranylidene)ammonium tetrahedro-nonacarbonyl(hydrido)(μ3-bis(diphenylphosphino)methane)tetrairidate(CAS DataBase Reference)
    10. NIST Chemistry Reference: bis(triphenylphosphoranylidene)ammonium tetrahedro-nonacarbonyl(hydrido)(μ3-bis(diphenylphosphino)methane)tetrairidate(286385-08-8)
    11. EPA Substance Registry System: bis(triphenylphosphoranylidene)ammonium tetrahedro-nonacarbonyl(hydrido)(μ3-bis(diphenylphosphino)methane)tetrairidate(286385-08-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 286385-08-8(Hazardous Substances Data)

286385-08-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 286385-08-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,8,6,3,8 and 5 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 286385-08:
(8*2)+(7*8)+(6*6)+(5*3)+(4*8)+(3*5)+(2*0)+(1*8)=178
178 % 10 = 8
So 286385-08-8 is a valid CAS Registry Number.

286385-08-8Downstream Products

286385-08-8Relevant articles and documents

Bis(diphosphino)methanide and hydride derivatives of Ir4(CO)I2

Detti, Serena,Lumini, Tito,Roulct, Raymond,Schenk, Kurt,Ros, Rcnzo,AugustoTassan

, p. 1645 - 1648 (2007/10/03)

The reaction of [Ir4(CO)10(u-(Ph2P)2CH2)] with dried KOH forms [Ir4(CO)10(n-(Ph2P)2CH)]~ which subsequently converts into [Ir4(CO)9(u3-(Ph2P)2CH)]-, a rare example of an Ir cluster with an Ir-C bond (average 2.274(8) A). The same reaction with the weaker base l,8-diazobicyclo[5.4.0]undec-7-ene or with K2CO3 in wet CH2C12 under CO affords the anion [HIr4(CO)9(u-(Ph2P)2CH2)]~, a hydride-cluster with an unusually long Ir-H distance (2.08(6) A at 90 K). Intramolecular CO scrambling is observed in CD2C12 solution above 200 K, preserving the terminal-axial position of the hydride ligand. The Royal Society of Chemistry 2000.

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