286401-36-3

Basic information

• Product Name: tris(m-fluorophenyl)antimony(V) bis(2-methoxybenzoate)
• CAS NO: 286401-36-3
• Molecular Weight: 709.322
• Mol File: 286401-36-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tris(m-fluorophenyl)antimony(V) bis(2-methoxybenzoate)(CAS DataBase Reference)
• NIST Chemistry Reference: tris(m-fluorophenyl)antimony(V) bis(2-methoxybenzoate)(286401-36-3)
• EPA Substance Registry System: tris(m-fluorophenyl)antimony(V) bis(2-methoxybenzoate)(286401-36-3)

Safety Data

• Hazardous Substances Data: 286401-36-3(Hazardous Substances Data)

Upstream product

• 159226-57-0 tris(m-fluorophenyl)antimony(V) dichloride 
• 17264-78-7 sodium 2-methoxybenzoate 

Relevant articles and documents

Fluorophenylantimony carboxylates. I. Synthesis and spectroscopic (UV, IR, 1H and 19F NMR) studies of some new monofluoro-and pentafluorophenylantimony(III and V) derivatives of 2-methoxybenzoic acid

A series of new mono-and pentafluorophenylantimony(III and V) arylcarboxylates of the type ArnSb(OOCC6H4OCH3-2)3-n and Ar3Sb(OOCC6H4OCH3-2)2 (Ar = p-FC6H4-, m-FC6H4-and C6F5-, n =1 or 2) have been synthesized by the reaction of fluorophenylantimony (III or V) chlorides and the sodium salt of 2-methoxybenzoic acid in the presence of 15-crown-5 as phase transfer catalyst. A representative compound, namely trimethylantimony(V) bis(2-methoxybenzoate) has also been synthesized for the sake of spectral comparisons. The van't Hoff factor 'i' and molar conductance data of the compounds revealed them to be monomeric and non-conducting in nature. The compounds were characterised by the usual physicochemical techniques e.g., elemental analyses, UV, IR and NMR (1H, 13C and 19F). Compound (III-VIII) are tentatively assigned as a trigonal bipyramidal structure in which the 2-methoxybenzoate acted as monodentate ligand.