28693-86-9Relevant academic research and scientific papers
Sequential double claisen rearrangement and two-directional ring-closing metathesis as a route to various benzofused bisoxepin and bisoxocin derivatives
Chattopadhyay, Shital K.,Biswas, Titas,Maity, Susama
, p. 2211 - 2214 (2007/10/03)
A synthetic strategy based on tandem application of double Claisen rearrangement and two-directional ring-closing metathesis reaction as key-steps has been developed for the synthesis of various hitherto unknown tri-, tetra- and pentacyclic benzofused bis
Combined Multiple Claisen Rearrangement and Ring-closing Metathesis as a Route to Naphthalene, Anthracene, and Anthracycline Ring Systems
Chattopadhyay, Shital K.,Pal, Benoy K.,Maity, Susama
, p. 1190 - 1191 (2007/10/03)
A new route involving double Claisen rearrangement of a suitable 1,4-diallyloxyarene system followed by ring-closing metathesis of the resulting diene has been developed for the synthesis of various benzannulated cyclohexenes. An important demonstration of this methodology is the construction of the tetracyclic quinophenolic ring system of the clinically important anthracyclines.
