287110-96-7Relevant academic research and scientific papers
Synthesis and novel reactivity of platinum phosphine-borane complexes trans-[PtH(PPhR·BH3)(PEt3)2] (R = H, Ph)
Dorn, Hendrik,Jaska, Cory A.,Singh, Ryan A.,Lough, Alan J.,Manners, Ian
, p. 1041 - 1042 (2007/10/03)
The oxidative-addition reaction of Pt(PEt3)3 with the phosphine-borane adducts PhPH2·BH3 and Ph2PH·BH3 leads to regioselective insertion of the Pt(PEt3)2 fragment into the P-H bond to afford the hydride complexes trans[PtH(PPhR·BH3)(PEt3)2] (R = H 1, R = Ph 2); reaction of 2 with PhPH2·BH3 leads to an unusual ligand exchange reaction which generates 1 and Ph2PH·BH3.
