28750-05-2Relevant academic research and scientific papers
DEFLUORINATION OF HEXADECAFLUOROBICYCLODEC-1-ENE: A FACILE SYNTHESIS OF PERFLUOROAROMATICS
Hu, Chang-Ming,Long, Fei,Xu, Ze-Qi
, p. 29 - 35 (2007/10/02)
Depending mainly on the polarity of the aprotic solvent used, defluorination of hexadecafluorobicyclodec-1(6)-ene (1) with activated zinc gave tetradecafluorobicyclodec-1(2),6(7)-diene (2), perfluorotetraline (3), decafluoro-1,2-dihydronaphthalene (4) and perfluoronaphthalene (5).In methanol, 2,7-dimethoxy-dodecafluorobicyclodec-1(2),6(7)-diene (6) was formed.These products were characterized by elemental analysis, IR, UV, 1H NMR and 19F NMR.An electron transfer and then a radical intermediate seem to be involved in such defluorination reactions.
