2876-80-4Relevant academic research and scientific papers
Copper-catalyzed highly efficient ester formation from carboxylic acids/esters and formates
Liu, Jun,Shao, Changdong,Zhang, Yanghui,Shi, Guangfa,Pan, Shulei
supporting information, p. 2637 - 2640 (2014/05/06)
A highly efficient copper-catalyzed protocol for the synthesis of esters has been developed from formates. This protocol is applicable to reactions with either esters or acids as the substrates, and shows broad substrate scopes and high yields. This journal is the Partner Organisations 2014.
Molybdenum hexacarbonyl mediated alkoxycarbonylation of aryl halides
Ren, Wei,Emi,Yamane, Motoki
experimental part, p. 2303 - 2309 (2011/09/19)
Mo(CO)mediates the alkoxycarbonylation of aryl halides in their reaction with alcohols to afford arenecarboxylic acid esters. The molybdenum carbonyl complexes act as the catalyst and the source with carbon monoxide. The alkoxycarbonylation proceeds with a small excess of carbon monoxide in the form of Mo(CO)and the procedure is simple compared to the conventional method, which uses palladium catalyst under gaseous carbon monoxide. Using this procedure, a variety of carboxylic acid esters were prepared. Georg Thieme Verlag Stuttgart ? New York.
