287735-76-6

Upstream product

• 873-51-8 phenylborondichloride 
• 7486-35-3 tri-n-butyl(vinyl)tin 

Downstream Products

• 287735-73-3 N-methylallylaminophenylvinylborane 
• 386708-29-8 (N-allyl,N-ethylamino)phenylvinylborane 
• 615253-88-8 1-ethyl-3-chlorodimethylsilyl-2,3-dihydro-2-phenyl-1H-1,2-azaborole 
• 615253-90-2 1-ethyl-3-(cyclopentadienyldimethylsilyl)-2,3-dihydro-2-phenyl-1H-1,2-azaborole 
• 615253-94-6 bis(1-ethyl-3-chlorodimethylsilyl-2,3-dihydro-2-phenyl-1H-1,2-azaborol-3-yl)dimethylsilane 
• 287735-74-4 1,5-dihydro-1-methyl-2-phenyl-1,2-azaborole 
• 615253-81-1 1-ethyl-2,5-dihydro-2-phenyl-1H-1,2-azaborole 

Relevant academic research and scientific papers

New heteroaromatic π-ligands containing boron

The heteroaromatic anions 2-(diisopropylamino)-1,2-thiaborolide(2a), 1-ethyl-2-phenyl-1,2-azaborolide(2b), and 2-(diisopropylamino)-1,2- oxaborolide(2c) have been prepared by a multi-step synthesis using the Grubbs ring-closing metathesis. Reactions of 2a

A synthesis of aromatic five- and six-membered B-N heterocycles via ring closing metathesis

equation presented The ring closing metathesis on appropriate vinyl or allyl aminoboranes (1 or 2) gives azaboracycloalkenes (3 or 4) which can be converted to azaborolides (5) or azaborines (6).