287934-39-8

Upstream product

• 295797-71-6 methyl (Z)-2-(6'-O-p-toluenesulfonyl-2',3',4',6'-tetra-O-acetyl-β-D-galactopyranosyloxy)-3-p-t-butyldimethylsilyloxyphenylacrylate 
• 295797-72-7 methyl (Z)-2-(6'-O-p-toluenesulfonyl-2',3',4',6'-tetra-O-acetyl-β-D-galactopyranosyloxy)-3-p-hydroxyphenylacrylate 
• 223930-89-0 (Z)-3-[4-(tert-Butyl-dimethyl-silanyloxy)-phenyl]-2-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-acrylic acid methyl ester 
• 295797-78-3 (Z)-3-[4-(tert-Butyl-dimethyl-silanyloxy)-phenyl]-2-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-acrylic acid methyl ester 
• 295797-73-8 methyl (Z)-2-(6'-azido-2',3',4',6'-tetra-O-acetyl-β-D-galactopyranosyloxy)-3-p-hydroxyphenylacrylate 
• 295797-77-2 (Z)-3-[4-(tert-Butyl-dimethyl-silanyloxy)-phenyl]-2-((2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-acrylic acid methyl ester 
• 295797-74-9 methyl (Z)-2-(6'-azido-β-D-galactopyranosyloxy)-3-p-hydroxyphenylacrylate 

Downstream Products

• 287934-47-8 methyl (Z)-2-[6'-(N-t-butoxycarbonylglycylglycylglycylamino)-β-D-galactopyranosyloxy]-3-p-hydroxyphenyl-acrylate 
• 397884-06-9 methyl (Z)-2-[6'-(6-((7-amino-4-methylcoumarin-3-acetyl)amino)-hexanamide)-β-D-galactopyranosyloxy]-3-p-hydroxyphenyl-acrylate 
• 397884-08-1 methyl (Z)-2-[6'-(6-(4-((5-dimethylaminonaphthalene-1-sulfonyl)amino))-hexanamide)-β-D-galactopyranosyloxy]-3-p-hydroxyphenyl-acrylate 
• 397884-07-0 methyl (Z)-2-[6'-(6-(N-(7-nitrobenz-2-oxa-1,3-diazol-4-yl)-amino)-hexanamide)-β-D-galactopyranosyloxy]-3-p-hydroxyphenyl-acrylate 
• 287934-42-3 methyl (Z)-2-[6'-(N-benzyloxycarbonylglycylamino)-β-D-galactopyranosyloxy]-3-p-hydroxyphenylacrylate 

Relevant academic research and scientific papers

Direct observation of the target cell for leaf-movement factor using novel fluorescence-labeled probe compounds: Fluorescence studies of nyctinasty in legumes. Part 1

We synthesized fluorescence-labeled probe compounds bearing AMCA (1), NBD (2), and dansyl (3) groups as the fluorescent functionality. In these probe compounds, NBD-type probe, 2, showed leaf-opening activity at 5×10-6 M. The bioactivity of 2 is one-fifth as strong as that of the natural product, potassium isolespedezate (6). We carried out the binding experiment using 1 in a plant body.

Fluorescence study on the nyctinasty of Cassia mimosoides L. using novel fluorescence-labeled probe compounds

We synthesized fluorescence-labeled probe compounds bearing 6-((7-amino-4-methylcoumarin-3-acetyl)amino)-hexanoyl (AMCA, 1), 6-N-(7-nitrobenz-2-oxa-1, 3-diazol-4-yl)-aminohexanoyl (NBD, 2), and 6-(4-((5-dimethylaminonaphthalene-1-sulfonyl)-amino))-hexanoyl (dansyl, 3) groups as the fluorescent functionality. In these probe compounds, NBD-type probe, 2, showed leaf-opening activity at 5×10-6 M. The bioactivity of 2 is one-fifth as strong as that of the natural product, potassium isolespedezate (6). We carried out the binding experiment using 1 in a plant body. Then, it was suggested that fluorescence-labeled probe compound directly bound to a motor cell in pulvina of Cassia mimosoides. And this binding was specific to C. mimosoides. Probe compounds cannot bind plant sections of other nyctinastic plants.

Synthetic probe compounds for bioorganic studies of nyctinasty, based on the leaf-opening substance of Lespedeza cuneata G. Don

In a previous paper, the syntheses of potassium galactolespedezate (1) and potassium galactoisolespedezate (2), artificial leaf-opening substances useful for bioorganic studies of nyctinasty were reported. The fluorescent probe compounds, fluorescence-labeled galactoisolespedezate (3) and iodo-one (4), designed on the basis of 1 and 2 were prepared. Especially, compound 3 was bioactive at 5x10-5 M, one-fiftieth as strong as the natural leaf-opening substance. This fluorescent probe would be useful for bioorganic studies of nyctinasty. (C) 2000 Elsevier Science Ltd.

Syntheses of fluorescence-labeled artificial leaf-opening substances, fluorescent probe compounds useful for bioorganic studies of nyctinasty

In a previous paper, the syntheses of potassium galactolespedezate (1) and potassium galactoisolespedezate (2), artificial leaf-opening substances useful for bioorganic studies of nyctinasty were reported. The fluorescent probe compounds, fluorescence-labeled galactoisolespedezates (3, 10, 13), designed on the basis of 1 and 2, were prepared. In particular, compound 3 was bioactive at 5 x 10-5 M, one-fiftieth as strong as the natural leaf- opening substance. This fluorescent probe would be useful for bioorganic studies of nyctinasty. (C) 2000 Elsevier Science Ltd.