287944-08-5Relevant academic research and scientific papers
Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with 1-alkenyl halides or triflates: Convenient synthesis of unsymmetrical 1,3-dienes via the borylation-coupling sequence
Takagi, Jun,Takahashi, Kou,Ishiyama, Tatsuo,Miyaura, Norio
, p. 8001 - 8006 (2007/10/03)
The synthesis of 1-alkenylboronic acid pinacol esters via a palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron (pin2B2, pin = Me4C2O2) with 1-alkenyl halides or triflates was carrie
Synthesis of alkenylboronates via palladium-catalyzed borylation of alkenyl triflates (or Iodides) with pinacolborane
Murata, Miki,Oyama, Takashi,Watanabe, Shinji,Masuda, Yuzuru
, p. 778 - 780 (2007/10/03)
Various alkenyl iodides and triflates were borylated with pinacolborane in the presence of Et3N and a catalytic amount of PdCl2(dppf) and AsPh3 to afford the corresponding alkenylboronates in good yields.
