287967-70-8Relevant academic research and scientific papers
Optically active asymmetric di(tertiary phosphines). Crystal and molecular structure of [SP-4-3-(Sp,S)]-{1-[(2-chlorophenyl)-methylphosphino]-2- (dimethylphosphino)benzene-P,P′}{1-[1-(dimethylamino)ethyl]naphthyl-C 2,N}palladium(II)
Chatterjee,George,Salem,Willis
, p. 1890 - 1896 (2001)
Mono-deprotonation of the bis(secondary phosphine) (Rp*,Rp*)- and (Rp*,Sp*)-1,2-phenylenebis(methylphosphine) has been achieved using potassium in liquid ammonia to give a ca. 4 : 1 mixture of (±)-1-(dimethylpho
Completely stereoselective synthesis of a chiral tetra(tertiary phosphine). Crystal and molecular structure of [OC-6-22(/?,/?)]-(±)-dichloro{l,2-bis[(2-dimethyIphosphinophenyl) methylphosphino]benzene-P,P',P",P'"}cobalt(ni) hexafluorophosphate f
Chatterjee, Swarup,Doyle, Roy,Hockless, David C. R.,Salem, Geoffrey,Willis, Anthony C.
, p. 1829 - 1830 (2007/10/03)
Reaction of (±)-(2-chlorophenyl)(2-dimethylphosphinophenyl)methylphosphine with sodium (2-dimethylphosphinophenyl)methylphosphide is completely stereoselective giving (.R,A)-l,2-bis[(2-dimethylphosphinophenyl)methylphosphino]benzene, (R,R)-1; as confirmed
