288098-53-3Relevant academic research and scientific papers
The reactions of N-substituted 2-(dimethylallyl)aniline compounds with phenylselanyl halides
Cooper, Matthew A.,Francis, Craig L.,Holman, Jeffrey W.,Kasum, Bruno,Taverner, Thomas,Tiekink, Edward R.T.,Ward, A. David
, p. 123 - 129 (2000)
Cyclization of the carbamate of 2-(dimethylallyl)aniline with phenylselanyl chloride (benzeneselenenyl chloride) gave a 1 : 1 mixture of a dihydroindole and a tetrahydroquinoline. With phenylselanyl bromide only the dihydroindole was obtained. Addition of
A convenient method for the aromatic amino-claisen rearrangement of N-(1,1-disubstituted-allyl)anilines
Cooper,Lucas,Taylor,Ward,Williamson
, p. 621 - 625 (2007/10/03)
N-(1,1-Disubstituted-allyl)anilines are rearranged cleanly and in high yield to 2-(3,3-disubstituted-allyl)anilines using a catalytic amount of p-toluenesulfonic acid in acetonitrile/water (10:1).
