288305-41-9Relevant academic research and scientific papers
Reactions of methyl(phenyl)silylene with CO and PH3-the formation of acid-base complexes
Bornemann, Holger,Sander, Wolfram
, p. 156 - 164 (2002)
The thermal reaction of methyl(phenyl)silylene 1a with CO and PH3, respectively, was investigated using matrix isolation spectroscopy in combination with DFT calculations. The silylene 1a was produced by UV irradiation (λ>400 nm followed by λ>3
Oxidation of methyl(phenyl)silylene - Synthesis of a dioxasilirane
Bornemann, Holger,Sander, Wolfram
, p. 6727 - 6734 (2007/10/03)
The oxidation of methyl(phenyl)silylene, 3f, with molecular oxygen is investigated using matrix isolation spectroscopy in combination with DFT calculations. The UV irradiation (λ > 305 nm) of phenylsilyldiazomethane, 8, matrix-isolated in argon at 10 K, p
