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1-Octadecanethiol (ODT) is a water-soluble sulfur compound with an 18-carbon alkyl chain, known for its strong hydrophobic assembly with transition metals, such as gold. It forms self-assembled monolayers (SAMs) on the surface of these transition metals, exhibiting an electrostriction phenomenon when covalently bonded with the metal electrode, leading to variations in capacitance. ODT SAMs have a hydrophobic surface with a contact angle of 102oC. It is a white powder with an extremely unpleasant smell.

2885-00-9

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2885-00-9 Usage

Uses

Used in Organic Synthesis:
Octadecanethiol is used as an organic intermediate for various chemical reactions and processes, contributing to the synthesis of different compounds.
Used in Synthetic Rubber Processing:
Octadecanethiol is utilized in the processing of synthetic rubber, enhancing its properties and performance in various applications.
Used in Surface Modification:
Octadecanethiol is used for surface modification of gold nanoparticles (AuNPs) and Nickel (Ni) foam conjugate, preparing a 3D surface-enhanced Raman spectroscopy (SERS) substrate for the detection of organic pollutants. It may also be used to enhance the superhydrophobic properties of different materials, such as nano-sized copper films, graphene, and silica, for applications like mercury detection and electrochemical analysis.
Used in Molecular Deposition:
1-Octadecanethiol (ODT) is employed to deposit thiolated molecules onto the surface of gold substrates, such as SAMs on gold quartz crystal resonators and on the tip of atomic force microscope probes, as well as capacitive sensors.

Reactivity Profile

Octadecanethiol is non-flammable but combustible (Flash point >100°F and <140°F). Incompatible with oxidizing agents, strong acids and strong bases, alkali metals, and nitric acid. Can react with water, steam or acids to produce toxic and flammable vapors. Reacts violently with powerful oxidizing agents such as calcium hypochlorite(Ca(OCl)2) to generate SOx. Reacts with hydrides to form flammable H2 gas; reacts with halogenated hydrocarbons to yield HX. Reacts exothermically with aldehydes. Emits toxic compounds of sulfur when when heated to decomposition.

Hazard

Strong irritant.

Flammability and Explosibility

Notclassified

Check Digit Verification of cas no

The CAS Registry Mumber 2885-00-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,8,8 and 5 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 2885-00:
(6*2)+(5*8)+(4*8)+(3*5)+(2*0)+(1*0)=99
99 % 10 = 9
So 2885-00-9 is a valid CAS Registry Number.
InChI:InChI=1/C18H38S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h19H,2-18H2,1H3

2885-00-9 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
  • Packaging
  • Price
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  • Alfa Aesar

  • (L04123)  1-Octadecanethiol, 96%   

  • 2885-00-9

  • 25g

  • 149.0CNY

  • Detail
  • Alfa Aesar

  • (L04123)  1-Octadecanethiol, 96%   

  • 2885-00-9

  • 100g

  • 417.0CNY

  • Detail
  • Aldrich

  • (O1858)  1-Octadecanethiol  98%

  • 2885-00-9

  • O1858-25ML

  • 359.19CNY

  • Detail
  • Aldrich

  • (O1858)  1-Octadecanethiol  98%

  • 2885-00-9

  • O1858-100ML

  • 993.33CNY

  • Detail
  • Sigma-Aldrich

  • (74731)  1-Octadecanethiol  purum, ≥95.0% (GC)

  • 2885-00-9

  • 74731-50G

  • 638.82CNY

  • Detail
  • Sigma-Aldrich

  • (74731)  1-Octadecanethiol  purum, ≥95.0% (GC)

  • 2885-00-9

  • 74731-250G

  • 2,387.97CNY

  • Detail

2885-00-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name Octadecanethiol

1.2 Other means of identification

Product number -
Other names MERCAPTAN C18

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2885-00-9 SDS

2885-00-9Relevant academic research and scientific papers

Amphiphilic dendrimer, synthesis method thereof, and application of amphiphilic dendrimer as drug delivery system

-

Paragraph 0096-0097; 0108-0110; 0123-0124; 0132-0134, (2021/08/07)

The invention relates to a microenvironment response type amphiphilic dendrimer, a synthesis method thereof, and application of the microenvironment response type amphiphilic dendrimer as a drug delivery system. The microenvironment response type amphiphilic dendrimer is a compound with a structure as shown in a formula (I), a formula (II) or a formula (III) or pharmaceutically acceptable salt of the compound. The compound disclosed by the invention can be used as the nano delivery system based on tumor microenvironment specific response, has good solubility in an aqueous solution, can be self-assembled with a drug in the aqueous solution to form a relatively stable nano compound, can effectively deliver the loaded drug to a tumor site; and can responsively disassembl the nano-drug delivery carrier under corresponding stimulation to achieve the purpose of accurate drug release, so that the drug can be released to the focus part to the greatest extent, and the compound is a novel nano-delivery carrier.

SYNTHETIC METHOD FOR THE PREPARATION OF 1, 2-BENZISOTHIAZOLIN-3-ONE

-

Paragraph 0263, (2015/12/05)

The present invention relates to a method for producing a 1,2-benzisothiazolin-3-one compound (I) by reacting a 2-halobenzonitrile compound (II) with a thiol compound (III) to form an intermediate (IV) and subsequently reacting the intermediate (IV) with a halogenation agent in the presence of water to form a reaction mixture (RM), comprising the 1,2-benzisothiazolin-3-one compound (I) and a halide compound (V).

Synthetic method for the preparation of 1,2-Benzisothiazolin-3-one

-

Paragraph 0158, (2015/12/18)

The present invention relates to a method for producing a 1,2-benzisothiazolin-3-one compound (I) by reacting a 2-halobenzonitrile compound (II) with a thiol compound (III) to form an intermediate (IV) and subsequently reacting the intermediate (IV) with a halogenation agent in the presence of water to form a reaction mixture (RM), comprising the 1,2-benzisothiazolin-3-one compound (I) and a halide compound (V). R3-SH (III), R3_X1(V),

3-(2-aminophenyl)-4-methyl-1,3-thiazole-2(3H)-thione as an ecofriendly sulphur transfer agent to prepare alkanethiols in high yield and high purity

Mehdid, Mohammed Amine,Djafri, Ayada,Roussel, Christian,Andreoli, Federico

experimental part, p. 4634 - 4643 (2010/04/06)

A new process is described for preparing very pure linear alkanethiols and linear α,ω-alkanedithiols using a sequential alkylation of the title compound, followed by a ring closure to quantitatively give the corresponding 3-methyl[1,3]thiazolo[3,2-a]-[3,1

L-Cysteine as a water-soluble cation scavenger in the removal of the 2,4,6-trimethoxybenzyl group from thiols

Lin, Chia-En,Richardson, Stewart K,Garvey, David S

, p. 4531 - 4533 (2007/10/03)

L-Cysteine was used as a water-soluble cation scavenger in the acid-catalyzed removal of the 2,4,6-trimethoxybenzyl (Tmob) group from thiols. After aqueous extraction, the product thiols were isolated in good yields. For most substrates, trifluoroacetic acid (TFA) is the reagent of choice. However, for the deprotection of acid-sensitive compounds, formic acid with an extended reaction time is appropriate.

Remarkably fast direct synthesis of thiols from alcohols under mild conditions

Bandgar,Sadavarte,Uppalla

, p. 1304 - 1305 (2007/10/03)

One pot rapid synthesis of thiols from alcohols via trifluoroacetates using polymer supported hydrosulfide in acetonitrile under mild conditions has been described.

Alkylthiopoly (ethylimidazolium) compounds, process for preparing them and their use as biocidal agents

-

, (2008/06/13)

The present invention relates to new cationic surfactant compounds of formula: STR1 in which: R1 denotes a C12 -C18 alkyl radical; R denotes methyl, ethyl, hydroxyethyl or benzyl; X denotes an inorganic or organic anion; n is between 2 and 15; w equals 0, 1 or 2; the group [C5 H6 N2 R+ ] representing the following structures, taken mixed or separately: STR2 as well as to their use as biocides.

Pesticidal compositions containing phosphoric esters and divalent sulphur compounds

-

, (2008/06/13)

Pesticidal composition comprising: a pesticidal, phosphoric ester the molecule of which has at least one alkyl group of 1 to 3 carbon atoms, 0.05 to 10% of an agent stabilizing the said ester against decomposition by protonisation, together with adjuvants characterized in that the stabilizing agent comprises at least one sulphur compound containing per molecule at least one divalent sulphur atom of which one valence is bonded to an atom chosen from sulphur, carbon, nitrogen, hydrogen, and metals capable of giving a salt, the other valence being bonded to an atom chosen from hydrogen, the carbon atom already noted, a second carbon atom, the nitrogen atom already noted, a second nitrogen atom, the metal atom already noted in the case of a metal of valence greater than one, a second atom of metal and oxygen when the first valence is not attached to an atom of hydrogen, the proportion of sulphur calculated with reference to the weight of the sulphur compound being between 5 and 99%. Process for stabilizing a phosphoric ester of which the molecule possesses at least one alkyl group containing 1 to 3 carbon atoms characterized in that there is added to the phosphoric ester or to a mixture which contains it, 0.05 to 10% calculated on the weight of the phosphoric acid ester of an agent capable of stabilizing the said phosphoric ester against protonisation and comprising at least one sulphur compound such as that defined thereupon.

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